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dc.contributor.authorWang, Jiangyan
dc.contributor.authorTang, Hongjie
dc.contributor.authorZhang, Lijuan
dc.contributor.authorRen, Hao
dc.contributor.authorYu, Ranbo
dc.contributor.authorJin, Quan
dc.contributor.authorQi, Jian
dc.contributor.authorMao, Dan
dc.contributor.authorYang, Mei
dc.contributor.authorWang, Yun
dc.contributor.authorLiu, Porun
dc.contributor.authorZhang, Yu
dc.contributor.authorWen, Yuren
dc.contributor.authorGu, Lin
dc.contributor.authorMa, Guanghui
dc.contributor.authorSu, Zhiguo
dc.contributor.authorTang, Zhiyong
dc.contributor.authorZhao, Huijun
dc.contributor.authorWang, Dan
dc.date.accessioned2017-11-29T12:00:41Z
dc.date.available2017-11-29T12:00:41Z
dc.date.issued2016
dc.identifier.issn2058-7546
dc.identifier.doi10.1038/nenergy.2016.50
dc.identifier.urihttp://hdl.handle.net/10072/100907
dc.description.abstractOne of the major problems in the development of lithium-ion batteries is the relatively low capacity of cathode materials compared to anode materials. Owing to its high theoretical capacity, vanadium oxide is widely considered as an attractive cathode candidate. However, the main hindrances for its application in batteries are its poor capacity retention and low rate capability. Here, we report the development of multi-shelled vanadium oxide hollow microspheres and their related electrochemical properties. In contrast to the conventional cation-adsorption process, in which the metal cations adsorb on negatively charged carbonaceous templates, our approach enables the adsorption of metal anions. We demonstrate controlled syntheses of several multi-shelled metal oxide hollow microspheres. In particular, the multi-shelled vanadium oxide hollow microspheres deliver a specific capacity of 447.9 and 402.4 mAh g−1 for the first and 100th cycle at 1,000 mA g−1, respectively. The significant performance improvement offers the potential to reduce the wide capacity gap often seen between the cathode and anode materials.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.publisherNature Publishing Group
dc.relation.ispartofpagefrom16050-1
dc.relation.ispartofpageto16050-9
dc.relation.ispartofjournalNature Energy
dc.relation.ispartofvolume1
dc.subject.fieldofresearchInorganic Green Chemistry
dc.subject.fieldofresearchElectrical and Electronic Engineering
dc.subject.fieldofresearchEnvironmental Engineering
dc.subject.fieldofresearchcode030203
dc.subject.fieldofresearchcode0906
dc.subject.fieldofresearchcode0907
dc.titleMulti-shelled metal oxides prepared via an anion-adsorption mechanism for lithium-ion batteries
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.hasfulltextNo Full Text
gro.griffith.authorZhao, Huijun
gro.griffith.authorLiu, Porun
gro.griffith.authorWang, Yun
gro.griffith.authorTang, Zhiyong
gro.griffith.authorWang, Dan


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