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dc.contributor.authorYan, Z
dc.contributor.authorYuan, Y
dc.contributor.authorTian, Y
dc.contributor.authorZhang, D
dc.contributor.authorZhu, G
dc.date.accessioned2018-01-23T00:27:44Z
dc.date.available2018-01-23T00:27:44Z
dc.date.issued2015
dc.identifier.issn1433-7851
dc.identifier.doi10.1002/anie.201503362
dc.identifier.urihttp://hdl.handle.net/10072/101423
dc.description.abstractThe targeted synthesis of a series of novel charged porous aromatic frameworks (PAFs) is reported. The compounds PAF-23, PAF-24, and PAF-25 are built up by a tetrahedral building unit, lithium tetrakis(4-iodophenyl)borate (LTIPB), and different alkyne monomers as linkers by a Sonogashira–Hagihara coupling reaction. They possess excellent adsorption properties to organic molecules owing to their “breathing” dynamic frameworks. As these PAF materials assemble three effective sorption sites, namely the ion bond, phenyl ring, and triple bond together, they exhibit high affinity and capacity for iodine molecules. To the best of our knowledge, these PAF materials give the highest adsorption values among all porous materials (zeolites, metal–organic frameworks, and porous organic frameworks) reported to date.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA
dc.relation.ispartofpagefrom12733
dc.relation.ispartofpageto12737
dc.relation.ispartofissue43
dc.relation.ispartofjournalAngewandte Chemie International Edition
dc.relation.ispartofvolume54
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchOther chemical sciences not elsewhere classified
dc.subject.fieldofresearchcode34
dc.subject.fieldofresearchcode349999
dc.titleHighly efficient enrichment of volatile iodine by charged porous aromatic frameworks with three sorption sites
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.facultyGriffith Sciences, Queensland Micro and Nanotechnology Centre
gro.hasfulltextNo Full Text
gro.griffith.authorYan, Zhuojun


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