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dc.contributor.authorVan Den Ancker, Tania
dc.contributor.authorRaston, Colin
dc.date.accessioned2019-05-24T02:59:18Z
dc.date.available2019-05-24T02:59:18Z
dc.date.issued1998
dc.identifier.issn0022328X
dc.identifier.doi10.1016/S0022-328X(97)00543-3
dc.identifier.urihttp://hdl.handle.net/10072/121571
dc.description.abstractHighly coloured paramagnetic polymer supported lithium 5,5′ and sodium 6,6′ naphthalenide complexes have been prepared from the reaction of THF solutions of lithium and sodium biphenylide with polystyrene bearing –CH2SiMe2(C10H7) groups. Treating chloropropyl functionalised silica, alumina and titania surfaces with H3Al·NMe3 or H3Ga·NMe3 afford hydroxyl depleted surfaces. Successive treatment with lithium biphenylide, 1-(chlorodimethylsilyl)naphthalene and an alkali biphenylide affords supported alkali naphthalenide complexes which generate in high yield lithium and sodium reagents when treated with a range of organic halides, nitriles and phosphates, as found for 6,6′ and 7,7′.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.publisherElsevier Science
dc.publisher.placeSwitzerland
dc.relation.ispartofpagefrom283
dc.relation.ispartofpageto300
dc.relation.ispartofissue1-2
dc.relation.ispartofjournalJournal of Organometallic Chemistry
dc.relation.ispartofvolume550
dc.subject.fieldofresearchInorganic Chemistry
dc.subject.fieldofresearchOrganic Chemistry
dc.subject.fieldofresearchOther Chemical Sciences
dc.subject.fieldofresearchcode0302
dc.subject.fieldofresearchcode0305
dc.subject.fieldofresearchcode0399
dc.titlePolymer and Metal Oxide Supported Alkali Metal Napathalenides: Application in the Generation of Lithium and Sodium Reagents
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.facultyArts, Education & Law Group, Griffith Institute of Higher Education
gro.hasfulltextNo Full Text
gro.griffith.authorRaston, Colin L.
gro.griffith.authorVan Den Ancker, Tania


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