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  • On the synergistic effect of hydrohalic acids in the shape-controlled synthesis of anatase TiO2 single crystals

    Author(s)
    Wu, Long
    Yang, Bing Xing
    Yang, Xiao Hua
    Chen, Zhi Gang
    Li, Zhen
    Zhao, Hui Jun
    Gong, Xue Qing
    Yang, Hua Gui
    Griffith University Author(s)
    Zhao, Huijun
    Yang, Huagui
    Year published
    2013
    Metadata
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    Abstract
    Cuboid-like anatase TiO2 single crystals bounded by {001} and {100} facets have been successfully synthesized with HCl as a synergistic capping agent together with HF, under the guidance of theoretical calculations. DFT calculations suggest that the preferred replacement of HCl with HF at (100) as well as its favorable adsorption provide a unique stabilization effect on the formation of cuboid-like anatase TiO2.Cuboid-like anatase TiO2 single crystals bounded by {001} and {100} facets have been successfully synthesized with HCl as a synergistic capping agent together with HF, under the guidance of theoretical calculations. DFT calculations suggest that the preferred replacement of HCl with HF at (100) as well as its favorable adsorption provide a unique stabilization effect on the formation of cuboid-like anatase TiO2.
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    Journal Title
    CrystEngComm
    Volume
    15
    Issue
    17
    DOI
    https://doi.org/10.1039/c2ce26744f
    Subject
    Inorganic chemistry
    Inorganic green chemistry
    Physical chemistry
    Electrochemistry
    Materials engineering
    Publication URI
    http://hdl.handle.net/10072/140389
    Collection
    • Journal articles

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