• myGriffith
    • Staff portal
    • Contact Us⌄
      • Future student enquiries 1800 677 728
      • Current student enquiries 1800 154 055
      • International enquiries +61 7 3735 6425
      • General enquiries 07 3735 7111
      • Online enquiries
      • Staff phonebook
    View Item 
    •   Home
    • Griffith Research Online
    • Journal articles
    • View Item
    • Home
    • Griffith Research Online
    • Journal articles
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

  • All of Griffith Research Online
    • Communities & Collections
    • Authors
    • By Issue Date
    • Titles
  • This Collection
    • Authors
    • By Issue Date
    • Titles
  • Statistics

  • Most Popular Items
  • Statistics by Country
  • Most Popular Authors
  • Support

  • Contact us
  • FAQs
  • Admin login

  • Login
  • Brucine salts of L-a-hydroxy acids: brucinium hydrogen (S)-malate penta-hydrate and anhydrous brucinium hydrogen (2R,3R)-tartrate at 130 K

    Thumbnail
    View/Open
    40081_1.pdf (193.3Kb)
    Author(s)
    Smith, G
    Wermuth, UD
    White, JM
    Griffith University Author(s)
    Wermuth, Urs D.
    Year published
    2006
    Metadata
    Show full item record
    Abstract
    The structures of two brucinium (2,3-dimeth�y-10-oxostrychnidinium) salts of the a-hydr�y acids l-malic acid and l-tartaric acid, namely brucinium hydrogen (S)-malate penta�drate, C23H27N2O4+烴H5O5-絈2O, (I), and anhydrous brucinium hydrogen (2R,3R)-tartrate, C23H27N2O4+烴H5O6-,(II), have been determined at 130 K. Compound (I) has two brucinium cations, two hydrogen malate anions and ten water mol�ules of solvation in the asymmetric unit, and forms an extensively hydrogen-bonded three-dimensional framework structure. In compound (II), the brucinium cations form the common undulating brucine sheet substructures, which accommodate ...
    View more >
    The structures of two brucinium (2,3-dimeth�y-10-oxostrychnidinium) salts of the a-hydr�y acids l-malic acid and l-tartaric acid, namely brucinium hydrogen (S)-malate penta�drate, C23H27N2O4+烴H5O5-絈2O, (I), and anhydrous brucinium hydrogen (2R,3R)-tartrate, C23H27N2O4+烴H5O6-,(II), have been determined at 130 K. Compound (I) has two brucinium cations, two hydrogen malate anions and ten water mol�ules of solvation in the asymmetric unit, and forms an extensively hydrogen-bonded three-dimensional framework structure. In compound (II), the brucinium cations form the common undulating brucine sheet substructures, which accommodate parallel chains of head-to-tail hydrogen-bonded tartrate anion species in the inter�itial cavities.
    View less >
    Journal Title
    Acta Crystallographica Section C, Crystal Structure Communications
    Volume
    62
    Publisher URI
    https://onlinelibrary.wiley.com/iucr/doi/10.1107/S0108270106017288
    DOI
    https://doi.org/10.1107/S0108270106017288
    Copyright Statement
    © 2006 International Union of Crystallography. Published by Blackwell Publishing Ltd. The attached file is reproduced here in accordance with the copyright policy of the publisher.Please refer to the journal's website for access to the definitive, published version.
    Subject
    Inorganic chemistry
    Physical chemistry
    Other chemical sciences
    Publication URI
    http://hdl.handle.net/10072/14293
    Collection
    • Journal articles

    Footer

    Disclaimer

    • Privacy policy
    • Copyright matters
    • CRICOS Provider - 00233E

    Tagline

    • Gold Coast
    • Logan
    • Brisbane - Queensland, Australia
    First Peoples of Australia
    • Aboriginal
    • Torres Strait Islander