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dc.contributor.authorSmith, G
dc.contributor.authorWermuth, UD
dc.contributor.authorWhite, JM
dc.date.accessioned2017-05-03T11:22:49Z
dc.date.available2017-05-03T11:22:49Z
dc.date.issued2006
dc.date.modified2009-09-24T05:55:09Z
dc.identifier.issn0108-2701
dc.identifier.doi10.1107/S0108270106017288
dc.identifier.urihttp://hdl.handle.net/10072/14293
dc.description.abstractThe structures of two brucinium (2,3-dimeth�y-10-oxostrychnidinium) salts of the a-hydr�y acids l-malic acid and l-tartaric acid, namely brucinium hydrogen (S)-malate penta�drate, C23H27N2O4+烴H5O5-絈2O, (I), and anhydrous brucinium hydrogen (2R,3R)-tartrate, C23H27N2O4+烴H5O6-,(II), have been determined at 130 K. Compound (I) has two brucinium cations, two hydrogen malate anions and ten water mol�ules of solvation in the asymmetric unit, and forms an extensively hydrogen-bonded three-dimensional framework structure. In compound (II), the brucinium cations form the common undulating brucine sheet substructures, which accommodate parallel chains of head-to-tail hydrogen-bonded tartrate anion species in the inter�itial cavities.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.format.extent197976 bytes
dc.format.mimetypeapplication/pdf
dc.languageEnglish
dc.language.isoeng
dc.publisherBlackwell Munksgaard
dc.publisher.placeCopenhagen, Denmark
dc.publisher.urihttps://onlinelibrary.wiley.com/iucr/doi/10.1107/S0108270106017288
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefromO353
dc.relation.ispartofpagetoO357
dc.relation.ispartofjournalActa Crystallographica Section C, Crystal Structure Communications
dc.relation.ispartofvolume62
dc.rights.retentionN
dc.subject.fieldofresearchInorganic chemistry
dc.subject.fieldofresearchPhysical chemistry
dc.subject.fieldofresearchOther chemical sciences
dc.subject.fieldofresearchcode3402
dc.subject.fieldofresearchcode3406
dc.subject.fieldofresearchcode3499
dc.titleBrucine salts of L-a-hydroxy acids: brucinium hydrogen (S)-malate penta-hydrate and anhydrous brucinium hydrogen (2R,3R)-tartrate at 130 K
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.rights.copyright© 2006 International Union of Crystallography. Published by Blackwell Publishing Ltd. The attached file is reproduced here in accordance with the copyright policy of the publisher.Please refer to the journal's website for access to the definitive, published version.
gro.date.issued2006
gro.hasfulltextFull Text
gro.griffith.authorWermuth, Urs D.


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