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dc.contributor.authorWilliams, Stephen R.
dc.contributor.authorBernhardt, Debra
dc.contributor.authorEvans, Denis J.
dc.date.accessioned2017-05-03T12:18:39Z
dc.date.available2017-05-03T12:18:39Z
dc.date.issued2006
dc.date.modified2009-10-01T05:56:10Z
dc.identifier.issn00219606
dc.identifier.doi10.1063/1.2196411
dc.identifier.urihttp://hdl.handle.net/10072/14330
dc.description.abstractA thermostatted dynamical model with five degrees of freedom is used to test the fluctuation relation of Evans and Searles (Omega-FR) and that of Gallavotti and Cohen (Lambda-FR). In the absence of an external driving field, the model generates a time-independent ergodic equilibrium state with two conjugate pairs of Lyapunov exponents. Each conjugate pair sums to zero. The fluctuation relations are tested numerically both near and far from equilibrium. As expected from previous work, near equilibrium the Omega-FR is verified by the simulation data while the Lambda-FR is not confirmed by the data. Far from equilibrium where a positive exponent in one of these conjugate pairs becomes negative, we test a conjecture regarding the Lambda-FR [Bonetto et al., Physica D 105, 226 (1997); Giuliani et al., J. Stat. Phys. 119, 909 (2005)]. It was conjectured that when the number of nontrivial Lyapunov exponents that are positive becomes less than the number of such negative exponents, then the form of the Lambda-FR needs to be corrected. We show that there is no evidence for this conjecture in the empirical data. In fact, when the correction factor differs from unity, the corrected form of Lambda-FR is less accurate than the uncorrected Lambda-FR. Also as the field increases the uncorrected Lambda-FR appears to be satisfied with increasing accuracy. The reason for this observation is likely to be that as the field increases, the argument of the Lambda-FR more and more accurately approximates the argument of the Omega-FR. Since the Omega-FR works for arbitrary field strengths, the uncorrected Lambda-FR appears to become ever more accurate as the field increases. The final piece of evidence against the conjecture is that when the smallest positive exponent changes sign, the conjecture predicts a discontinuous change in the "correction factor" for Lambda-FR. We see no evidence for a discontinuity at this field strength.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.format.extent1004306 bytes
dc.format.mimetypeapplication/pdf
dc.languageEnglish
dc.language.isoeng
dc.publisherAmerican Institute of Physics
dc.publisher.placeMelville, NY
dc.publisher.urihttp://jcp.aip.org/
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom1941021
dc.relation.ispartofpageto1941029
dc.relation.ispartofjournalThe Journal of Chemical Physics
dc.relation.ispartofvolume124
dc.rights.retentionY
dc.subject.fieldofresearchPhysical sciences
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchEngineering
dc.subject.fieldofresearchcode51
dc.subject.fieldofresearchcode34
dc.subject.fieldofresearchcode40
dc.titleNumerical study of the steady state fluctuation relations far from equilibrium
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.rights.copyright© 2006 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in The Journal of Chemical Physics and may be found at http://jcp.aip.org/
gro.date.issued2006
gro.hasfulltextFull Text
gro.griffith.authorBernhardt, Debra J.


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