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dc.contributor.authorBott, Raymond C
dc.contributor.authorHealy, Peter C
dc.contributor.authorSmith, Graham
dc.date.accessioned2017-05-03T11:10:21Z
dc.date.available2017-05-03T11:10:21Z
dc.date.issued2007
dc.date.modified2009-08-25T03:45:35Z
dc.identifier.issn0277-5387
dc.identifier.doi10.1016/j.poly.2007.01.014
dc.identifier.urihttp://hdl.handle.net/10072/15090
dc.description.abstractA series of five gold(I) halide complexes with the two isomeric methoxy-substituted triarylphosphines, tris(2-methoxyphenyl)phosphine [P(oanis)3], [AuP(oanis)3X] [for X = Cl, (1); X = Br, (2) and X = I, (3)] and tris(4-methoxyphenyl)phosphine [P(panis)3], [AuP(panis)3X] [for X = Br (4) and X = I (5)] have been synthesized and characterized by single crystal X-ray diffraction and solution 31P{1H} NMR spectroscopy. The structure determinations confirm the expected presence of linear two-coordination about the gold centres in all five complexes with bond distance and angle data typical of this type of compound [Au-P, 2.239(2)-2.259(3) Ż Au-Cl, 2.294(2) Ż Au-Br, 2.385(2)-2.402(2) Ż Au-I, 2.546(1)-2.554(1) Ż P-Au-X; 175.3(1)-180ݮ All analogues except the iodo complex 5 crystallize with one complex molecule in the crystallographic asymmetric unit. The bromo and iodo complexes 2 and 3 constitute a trigonal isomorphous set while the bromo complex 4 is also isomorphous with the previously determined chloro complex [AuP(panis)3Cl]. The 2-methoxy analogues are stabilized by significant methoxy-Ocdots, three dots, centeredAu interactions.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoen_AU
dc.publisherElsevier BV
dc.publisher.placeNetherlands
dc.publisher.urihttp://www.sciencedirect.com/science/journal/02775387
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom2803
dc.relation.ispartofpageto2809
dc.relation.ispartofissue12
dc.relation.ispartofjournalPolyhedron
dc.relation.ispartofvolume26
dc.rights.retentionY
dc.subject.fieldofresearchInorganic Chemistry
dc.subject.fieldofresearchPhysical Chemistry (incl. Structural)
dc.subject.fieldofresearchOther Chemical Sciences
dc.subject.fieldofresearchcode0302
dc.subject.fieldofresearchcode0306
dc.subject.fieldofresearchcode0399
dc.titleStructural studies of two-coordinate complexes of tris(2-methoxylphenyl)phosphine and tris(4-methoxyphenyl)phosphine with gold(I) halides
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.rights.copyright© 2007 Elsevier. Please refer to the journal's website for access to the definitive, published version.
gro.date.issued2007
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.
gro.griffith.authorBott, Raymond
gro.griffith.authorSmith, Graham


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