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dc.contributor.authorBowmaker, GA
dc.contributor.authorde Silva, EN
dc.contributor.authorHealy, PC
dc.contributor.authorSkelton, BW
dc.contributor.authorWhite, AH
dc.date.accessioned2017-05-03T13:43:31Z
dc.date.available2017-05-03T13:43:31Z
dc.date.issued1999
dc.date.modified2009-08-21T06:38:54Z
dc.identifier.issn0300-9246
dc.identifier.doi10.1039/a808778d
dc.identifier.urihttp://hdl.handle.net/10072/15552
dc.description.abstractNew copper(I) and silver(I) halide-trimethylphosphine adducts have been prepared by reaction of MX with PMe3 in benzene suspension, and characterised by room-temperature single-crystal X-ray studies and/or solid state CP MAS 31P NMR and vibrational spectroscopy. The complex [Ag4Cl4(PMe3)3] is a one-dimensional polymer of quasi-cubanoid Ag4Cl4 units disposed with their body diagonals coincident with the crystallographic 3 axis, and linked by Ag-Cl units between the four-co-ordinate apical atoms of successive Ag4Cl4 units, isomorphous with its Cu counterpart. The first solid state NMR study of Cu/Ag PMe3 complexes is reported. The CP MAS 31P NMR and the far-IR and Raman spectra of the complexes [{CuI(PMe3)}4], [CuCl(PMe3)3] and [{AgX(PMe3)2}2] (X = Cl or Br) show the structures to be tetrameric cubane, monomeric pseudo-tetrahedral and dimeric halide-bridged respectively.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.publisher.placeUK
dc.publisher.urihttp://www.rsc.org/Publishing/Journals/dt/index.asp
dc.relation.ispartofpagefrom901
dc.relation.ispartofpageto908
dc.relation.ispartofjournalJournal of the Chemical Society. Dalton Transactions
dc.relation.ispartofvolume1999
dc.subject.fieldofresearchInorganic Chemistry
dc.subject.fieldofresearchOther Chemical Sciences
dc.subject.fieldofresearchTheoretical and Computational Chemistry
dc.subject.fieldofresearchcode0302
dc.subject.fieldofresearchcode0399
dc.subject.fieldofresearchcode0307
dc.titleStructural, Vibrational and Solid State CP/MAS31P NMR Spectroscopic Studies of Complexes of Trimethylphosphine with Copper(I) and Silver(I) Halides
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.rights.copyright© 1999 Royal Society of Chemistry. Please refer to the journal link for access to the definitive, published version.
gro.date.issued1999
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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