dc.contributor.author | Bowmaker, GA | |
dc.contributor.author | de Silva, EN | |
dc.contributor.author | Healy, PC | |
dc.contributor.author | Skelton, BW | |
dc.contributor.author | White, AH | |
dc.date.accessioned | 2017-05-03T13:43:31Z | |
dc.date.available | 2017-05-03T13:43:31Z | |
dc.date.issued | 1999 | |
dc.date.modified | 2009-08-21T06:38:54Z | |
dc.identifier.issn | 0300-9246 | |
dc.identifier.doi | 10.1039/a808778d | |
dc.identifier.uri | http://hdl.handle.net/10072/15552 | |
dc.description.abstract | New copper(I) and silver(I) halide-trimethylphosphine adducts have been prepared by reaction of MX with PMe3 in benzene suspension, and characterised by room-temperature single-crystal X-ray studies and/or solid state CP MAS 31P NMR and vibrational spectroscopy. The complex [Ag4Cl4(PMe3)3] is a one-dimensional polymer of quasi-cubanoid Ag4Cl4 units disposed with their body diagonals coincident with the crystallographic 3 axis, and linked by Ag-Cl units between the four-co-ordinate apical atoms of successive Ag4Cl4 units, isomorphous with its Cu counterpart. The first solid state NMR study of Cu/Ag PMe3 complexes is reported. The CP MAS 31P NMR and the far-IR and Raman spectra of the complexes [{CuI(PMe3)}4], [CuCl(PMe3)3] and [{AgX(PMe3)2}2] (X = Cl or Br) show the structures to be tetrameric cubane, monomeric pseudo-tetrahedral and dimeric halide-bridged respectively. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | Royal Society of Chemistry | |
dc.publisher.place | UK | |
dc.publisher.uri | http://www.rsc.org/Publishing/Journals/dt/index.asp | |
dc.relation.ispartofpagefrom | 901 | |
dc.relation.ispartofpageto | 908 | |
dc.relation.ispartofjournal | Journal of the Chemical Society. Dalton Transactions | |
dc.relation.ispartofvolume | 1999 | |
dc.subject.fieldofresearch | Inorganic Chemistry | |
dc.subject.fieldofresearch | Other Chemical Sciences | |
dc.subject.fieldofresearch | Theoretical and Computational Chemistry | |
dc.subject.fieldofresearchcode | 0302 | |
dc.subject.fieldofresearchcode | 0399 | |
dc.subject.fieldofresearchcode | 0307 | |
dc.title | Structural, Vibrational and Solid State CP/MAS31P NMR Spectroscopic Studies of Complexes of Trimethylphosphine with Copper(I) and Silver(I) Halides | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.rights.copyright | © 1999 Royal Society of Chemistry. Please refer to the journal link for access to the definitive, published version. | |
gro.date.issued | 1999 | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |