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  • A novel low density metal–organic framework with pcu topology by dendritic ligand

    Author(s)
    Jia, Jiangtao
    Sun, Fuxing
    Fang, Qianrong
    Liang, Xiaoqiang
    Cai, Kun
    Bian, Zheng
    Zhao, Huijun
    Gao, Lianxun
    Zhu, Guangshan
    Griffith University Author(s)
    Zhao, Huijun
    Zhu, Guangshan
    Year published
    2011
    Metadata
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    Abstract
    A novel low density two-fold interpenetrated MOF-5 analogue with pcu topology, JUC-100, was designed and prepared successfully. It can be regarded as MOF-5 in which half of the Zn4O(CO2)6 units are replaced by organic 1,3,5-triphenylbenzene segments. JUC-100 exhibits H2 uptake ability comparable to interpenetrated MOF-5, but relatively low initial isosteric heat of adsorption.A novel low density two-fold interpenetrated MOF-5 analogue with pcu topology, JUC-100, was designed and prepared successfully. It can be regarded as MOF-5 in which half of the Zn4O(CO2)6 units are replaced by organic 1,3,5-triphenylbenzene segments. JUC-100 exhibits H2 uptake ability comparable to interpenetrated MOF-5, but relatively low initial isosteric heat of adsorption.
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    Journal Title
    Chemical Communications
    Volume
    47
    Issue
    32
    DOI
    https://doi.org/10.1039/C1CC12891D
    Subject
    Inorganic Chemistry not elsewhere classified
    Chemical Sciences
    Publication URI
    http://hdl.handle.net/10072/166794
    Collection
    • Journal articles

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