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dc.contributor.authorD. Hartnell, Regan
dc.contributor.authorP. Arnold, Dennis
dc.date.accessioned2017-05-03T14:36:54Z
dc.date.available2017-05-03T14:36:54Z
dc.date.issued2004
dc.date.modified2009-09-21T05:51:06Z
dc.identifier.issn02767333
dc.identifier.doi10.1021/om0305869
dc.identifier.urihttp://hdl.handle.net/10072/16691
dc.description.abstractThe modification of peripherally metalated meso-?(1)-platiniometalloporphyrins, such as trans-[PtBr(NiDAPP)(PPh3)(2)] (H(2)DAPP = 5-phenyl-10,20-bis(3',5'-di-tert-butylphenyl)porphyrin), leads to the analogous platinum(II) nitrato and triflato electrophiles in almost quantitative yields. Self-assembly reactions of these meso-platinioporphyrin tectons with pyridine, 4,4'-bipyridine, or various meso-4-pyridylporphyrins in chloroform generate new multicomponent organometallic porphyrin arrays containing up to five porphyrin units. These new types of supramolecular arrays are formed exclusively in high yields and are stable in solution or in the solid state for extended periods. They were characterized by multinuclear NMR and UV-visible spectroscopy as well as high-resolution electrospray ionization mass spectrometry.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.publisher.placeWashington, DC
dc.publisher.urihttp://pubs.acs.org/journal/orgnd7
dc.relation.ispartofpagefrom391
dc.relation.ispartofpageto399
dc.relation.ispartofissue3
dc.relation.ispartofjournalOrganometallics
dc.relation.ispartofvolume23
dc.subject.fieldofresearchInorganic Chemistry
dc.subject.fieldofresearchOrganic Chemistry
dc.subject.fieldofresearchOther Chemical Sciences
dc.subject.fieldofresearchcode0302
dc.subject.fieldofresearchcode0305
dc.subject.fieldofresearchcode0399
dc.titlePeripherally η1-platinated organometallic porphyrins as building blocks for multiporphyrin arrays
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2004
gro.hasfulltextNo Full Text
gro.griffith.authorHartnell, Regan D.


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