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dc.contributor.authorLing, Min
dc.contributor.authorQiu, Jingxia
dc.contributor.authorLi, Sheng
dc.contributor.authorYan, Cheng
dc.contributor.authorKiefel, Milton J
dc.contributor.authorLiu, Gao
dc.contributor.authorZhang, Shanqing
dc.contributor.editorA. Paul Alivisatos & Charles M. Lieber
dc.date.accessioned2018-01-03T03:35:59Z
dc.date.available2018-01-03T03:35:59Z
dc.date.issued2015
dc.identifier.issn1530-6984
dc.identifier.doi10.1021/acs.nanolett.5b00795
dc.identifier.urihttp://hdl.handle.net/10072/167171
dc.description.abstractAn environmentally benign, highly conductive, and mechanically strong binder system can overcome the dilemma of low conductivity and insufficient mechanical stability of the electrodes to achieve high performance lithium ion batteries (LIBs) at a low cost and in a sustainable way. In this work, the naturally occurring binder sodium alginate (SA) is functionalized with 3,4-propylenedioxythiophene-2,5-dicarboxylic acid (ProDOT) via a one-step esterification reaction in a cyclohexane/dodecyl benzenesulfonic acid (DBSA)/water microemulsion system, resulting in a multifunctional polymer binder, that is, SA-PProDOT. With the synergetic effects of the functional groups (e.g., carboxyl, hydroxyl, and ester groups), the resultant SA-PProDOT polymer not only maintains the outstanding binding capabilities of sodium alginate but also enhances the mechanical integrity and lithium ion diffusion coefficient in the LiFePO4 (LFP) electrode during the operation of the batteries. Because of the conjugated network of the PProDOT and the lithium doping under the battery environment, the SA-PProDOT becomes conductive and matches the conductivity needed for LiFePO4 LIBs. Without the need of conductive additives such as carbon black, the resultant batteries have achieved the theoretical specific capacity of LiFePO4 cathode (ca. 170 mAh/g) at C/10 and ca. 120 mAh/g at 1C for more than 400 cycles.
dc.description.peerreviewedYes
dc.languageEnglish
dc.publisherAmerican Chemical Society
dc.publisher.placeUnited States
dc.relation.ispartofpagefrom4440
dc.relation.ispartofpageto4447
dc.relation.ispartofissue7
dc.relation.ispartofjournalNano Letters
dc.relation.ispartofvolume15
dc.subject.fieldofresearchChemical Characterisation of Materials
dc.subject.fieldofresearchOrganic Chemical Synthesis
dc.subject.fieldofresearchcode030301
dc.subject.fieldofresearchcode030503
dc.titleMultifunctional SA-PProDOT Binder for Lithium Ion Batteries
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.facultyGriffith Sciences, Griffith School of Environment
gro.hasfulltextNo Full Text
gro.griffith.authorZhang, Shanqing
gro.griffith.authorKiefel, Milton
gro.griffith.authorQiu, Jingxia
gro.griffith.authorLi, Sheng
gro.griffith.authorLing, Min


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