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  • "Raisin Bun"-like Nanocomposites of Palladium Clusters and Porphyrin for Superior Formic Acid Oxidation

    Author(s)
    Wang, Xiuxin
    Yang, Jiandong
    Yin, Huajie
    Song, Rui
    Tang, Zhiyong
    Griffith University Author(s)
    Tang, Zhiyong
    Yin, Huajie
    Year published
    2013
    Metadata
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    Abstract
    A novel “raisin bun”-like nanocomposite, where Pd clusters are embedded in porphyrin matrix, is developed as a promising electrocatalyst. Thanks to the synergy between the Pd clusters and the porphyrin matrix, this composite exhibits a low oxidation potential, high mass activity and excellent stability toward electrochemical oxidation of formic acid, which opens new routes for the design of high-performance catalysts in fuel cells.A novel “raisin bun”-like nanocomposite, where Pd clusters are embedded in porphyrin matrix, is developed as a promising electrocatalyst. Thanks to the synergy between the Pd clusters and the porphyrin matrix, this composite exhibits a low oxidation potential, high mass activity and excellent stability toward electrochemical oxidation of formic acid, which opens new routes for the design of high-performance catalysts in fuel cells.
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    Journal Title
    Advanced Materials
    Volume
    25
    Issue
    19
    DOI
    https://doi.org/10.1002/adma.201205168
    Subject
    Physical sciences
    Chemical sciences
    Engineering
    Materials engineering not elsewhere classified
    Publication URI
    http://hdl.handle.net/10072/172664
    Collection
    • Journal articles

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