Photoelectrochemical sensing of glucose based on quantum dot and enzyme nanocomposites
Author(s)
Zheng, Min
Cui, Yan
Li, Xinyu
Liu, Shaoqin
Tang, Zhiyong
Griffith University Author(s)
Year published
2011
Metadata
Show full item recordAbstract
A simple procedure for constructing the photoelectrochemical biosensor based on TiO2/CdSe@CdS QD nanocomposite modified electrode was developed. The TiO2/CdSe@CdS QD nanocomposite modified electrode was obtained by alternately depositing water-soluble CdSe@CdS QD and a mixture of [cobalt(o-phen)3]2+/3+ and poly(ethyleneimine) (PEI) over mesoscopic TiO2 films. The obtained TiO2/CdSe@CdS QD nanocomposite modified electrode exhibits much higher and stable photocurrent intensity than that of the photoelectrochemical biosensors reported so far. After the TiO2/CdSe@CdS QD nanocomposite modified electrode was coated with glucose ...
View more >A simple procedure for constructing the photoelectrochemical biosensor based on TiO2/CdSe@CdS QD nanocomposite modified electrode was developed. The TiO2/CdSe@CdS QD nanocomposite modified electrode was obtained by alternately depositing water-soluble CdSe@CdS QD and a mixture of [cobalt(o-phen)3]2+/3+ and poly(ethyleneimine) (PEI) over mesoscopic TiO2 films. The obtained TiO2/CdSe@CdS QD nanocomposite modified electrode exhibits much higher and stable photocurrent intensity than that of the photoelectrochemical biosensors reported so far. After the TiO2/CdSe@CdS QD nanocomposite modified electrode was coated with glucose oxidase, the photocurrent intensity was enhanced towards the addition of glucose. Thus, a photoelectrochemical biosensor for the detection of glucose was developed by monitoring the changes in the photocurrent intensity. Moreover, the proposed biosensor possessed good reproducibility and storage stability. Combining TiO2/CdSe@CdS nanocomposite and other biomolecules could be extended readily for sensing other biorecognition events.
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View more >A simple procedure for constructing the photoelectrochemical biosensor based on TiO2/CdSe@CdS QD nanocomposite modified electrode was developed. The TiO2/CdSe@CdS QD nanocomposite modified electrode was obtained by alternately depositing water-soluble CdSe@CdS QD and a mixture of [cobalt(o-phen)3]2+/3+ and poly(ethyleneimine) (PEI) over mesoscopic TiO2 films. The obtained TiO2/CdSe@CdS QD nanocomposite modified electrode exhibits much higher and stable photocurrent intensity than that of the photoelectrochemical biosensors reported so far. After the TiO2/CdSe@CdS QD nanocomposite modified electrode was coated with glucose oxidase, the photocurrent intensity was enhanced towards the addition of glucose. Thus, a photoelectrochemical biosensor for the detection of glucose was developed by monitoring the changes in the photocurrent intensity. Moreover, the proposed biosensor possessed good reproducibility and storage stability. Combining TiO2/CdSe@CdS nanocomposite and other biomolecules could be extended readily for sensing other biorecognition events.
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Journal Title
Journal of Electroanalytical Chemistry
Volume
656
Issue
1-2
Subject
Analytical chemistry
Analytical chemistry not elsewhere classified
Macromolecular and materials chemistry
Theoretical and computational chemistry