dc.contributor.author | Smith, Graham | |
dc.contributor.author | Wermuth, Urs D | |
dc.contributor.author | White, Jonathan M | |
dc.date.accessioned | 2017-05-03T11:22:52Z | |
dc.date.available | 2017-05-03T11:22:52Z | |
dc.date.issued | 2007 | |
dc.date.modified | 2009-09-24T05:51:54Z | |
dc.identifier.issn | 2056-9890 | |
dc.identifier.doi | 10.1107/S1600536807038068 | |
dc.identifier.uri | http://hdl.handle.net/10072/17598 | |
dc.description.abstract | (2,4,6-Trinitrophenyl)guanidine (picrylguanidine), C7H6N6O6, from the reaction of picrylsulfonic acid with guanidine carbonate, forms a three-dimensional framework structure through extensive hydrogen-bonding interactions, extending the centrosymmetric cyclic R22(16) dimer association which includes duplex R22(8) guanidine N-H...Onitro interactions. The guanidine substituent chain has an endo [Ph-N=C(NH2)2] bond sequence rather than the less sterically encumbered exo [Ph-NH-C=NH(NH2)] sequence of the tautomeric form. As a result, there is significant bond-angle distortion about C(-N=) of the aromatic ring. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.format.extent | 1992839 bytes | |
dc.format.mimetype | application/pdf | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | Blackwell Munksgaard | |
dc.publisher.place | Copenhagen, Denmark | |
dc.publisher.uri | https://doi.org/10.1107/S1600536807038068 | |
dc.relation.ispartofstudentpublication | N | |
dc.relation.ispartofpagefrom | O3759 | |
dc.relation.ispartofpageto | O3759 | |
dc.relation.ispartofissue | 9 | |
dc.relation.ispartofjournal | Acta Crystallographica Section E, Structure Reports Online | |
dc.relation.ispartofvolume | E63 | |
dc.rights.retention | Y | |
dc.subject.fieldofresearch | Chemical Sciences | |
dc.subject.fieldofresearchcode | 03 | |
dc.title | (2,4,6-Trinitrophenyl)guanidine | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
dcterms.license | http://creativecommons.org/licenses/by/2.0/uk/legalcode | |
gro.rights.copyright | © The Author(s) 2007. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode | |
gro.date.issued | 2007 | |
gro.hasfulltext | Full Text | |
gro.griffith.author | Wermuth, Urs D. | |