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dc.contributor.authorJenkins, Ian
dc.date.accessioned2019-05-17T01:02:39Z
dc.date.available2019-05-17T01:02:39Z
dc.date.issued1995
dc.identifier.issn0471936235en_US
dc.identifier.doi10.1002/047084289X.ro021en_US
dc.identifier.urihttp://hdl.handle.net/10072/177446
dc.description.abstract[55881‐03‐3] C12H36B2F8N6OP2 (MW 516.10) InChI = 1S/C12H36N6OP2.2BF4/c1‐13(2)20(14(3)4,15(5)6)19‐21(16(7)8,17(9)10)18(11)12;2*2‐1(3,4)5/h1‐12H3;;/q+2;2*‐1 InChIKey = MSSSPRSPUHPRKJ‐UHFFFAOYSA‐N (a mild dehydrating agent, useful in peptide synthesis,2 dehydration of aldoximes to nitriles3 and Beckmann or Lossen‐type rearangements3) Alternate Name: Bates’ reagent. Physical Data: mp 194–204 °C. Solubility: insol ether, EtOAc, THF, CH2Cl2, CHCl3; sol MeCN, DMF, HMPA. Form Supplied in: white crystalline solid; limited commercial availability. Preparative Methods: by treatment of Hexamethylphosphoric Triamide with p‐toluenesulfonic anhydride at 55 °C for 3 h, isolation of the bis(p‐toluenesulfonate), then treatment with NaBF4 in MeCN.2 Handling, Storage, and Precautions: can be used with care without special precautions; however, it reacts with water to produce HMPA (carcinogenic) and HBF4 (corrosive).en_US
dc.languageEnglishen_US
dc.publisherWileyen_US
dc.publisher.placeUSAen_US
dc.relation.ispartofpagefrom3822en_US
dc.relation.ispartofpageto3823en_US
dc.relation.ispartofissue1en_US
dc.relation.ispartofjournalEncyclopedia of Reagents for Organic Synthesisen_US
dc.subject.fieldofresearchCHEMICAL SCIENCESen_US
dc.subject.fieldofresearchcode030000en_US
dc.titleOxobis[tris Dimethylamino Phosphonium] Bis(Tetrafluoroborate)en_US
dc.typeJournal articleen_US
dc.type.descriptionC3 - Letter or Noteen_US
dc.type.codeC - Journal Articlesen_US
gro.hasfulltextNo Full Text
gro.griffith.authorJenkins, Ian D.


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