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dc.contributor.authorHEALY, PC
dc.contributor.authorKEPERT, DL
dc.contributor.authorTAYLOR, D
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:08:57Z
dc.date.available2017-05-03T11:08:57Z
dc.date.issued1973
dc.date.modified2009-08-21T06:34:03Z
dc.identifier.issn0300-9246
dc.identifier.doi10.1039/DT9730000646
dc.identifier.urihttp://hdl.handle.net/10072/19537
dc.description.abstractThe crystal structures of the title compounds have been determined from single-crystal photographic X-ray diffraction data by Patterson and Fourier techniques, and refined by block-diagonal least-squares methods. Cs2[(W6Cl8)Br6] : trigonal, P31c, a= 10簷 ᠰ簳, c= 14緵 ᠰ簱 Ż Z= 2; R= 0籱 for 665 observed reflections. Cs2[(Mo6Cl8)Br6] : trigonal, P31c, a= 10簶 ᠰ簲, c= 14緰 ᠰ簱 Ŭ Z= 2; R 0籲 for 598 observed reflections.The anion consists of an octahedral cluster of metal atoms with the chlorine atoms bridging the octahedral faces and the bromine atoms axially co-ordinated to the M6 core. The mean metal-metal distances are W-W 2網0 ᠰ簰7 and Mo-Mo 2綱5 ᠰ簰6 Ů Other bonding distances are as expected. Implications of the structure concerning the vibrational spectrum are discussed. Cell dimensions are given for the range of isomorphous complexes Cs2[(M6Cl8)Y6], M = Mo or W; Y = Cl, Br, or I.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoen_AU
dc.publisherRoyal Society of Chemistry
dc.publisher.placeUnited Kingdom
dc.publisher.urihttp://www.rsc.org/publishing/journals/DT/
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom646
dc.relation.ispartofpageto650
dc.relation.ispartofissue6
dc.relation.ispartofjournalJournal of the Chemical Society : Dalton Transactions : Inorganic Chemistry
dc.relation.ispartofvolume1973
dc.rights.retentionY
dc.subject.fieldofresearchcode250105
dc.titleCrystal structure of dicaesium octa-µ3-chloro-hexachloro-octahedro-hexa-tungstate(II) and -molybdate(II) complexes
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.rights.copyright© 1973 Royal Society of Chemistry. Please refer to the journal link for access to the definitive, published version.
gro.date.issued1973
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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