Manganese(IV) dithiocarbamato complexes
Author(s)
BROWN, KL
GOLDING, RM
HEALY, PC
JESSOP, KJ
TENNANT, WC
Griffith University Author(s)
Year published
1974
Metadata
Show full item recordAbstract
Several new cationic dithiocarbamato complexes of the type [Mn(dtc),] X (where dtc refers to the dithiocarbamate ligand and X to the non-coordinating anions, perchlorate and tetrafluoroborate) have been prepared by the reaction of manganous perchlorate and manganous tetrafluoroborate with the appropriate N,N-disubstituted dithiocarbamates. Conductivity, infrared, em., magnetic susceptibility and a complete structure determination on one of the compounds support a manganese(1v) formulation for the complexes.Several new cationic dithiocarbamato complexes of the type [Mn(dtc),] X (where dtc refers to the dithiocarbamate ligand and X to the non-coordinating anions, perchlorate and tetrafluoroborate) have been prepared by the reaction of manganous perchlorate and manganous tetrafluoroborate with the appropriate N,N-disubstituted dithiocarbamates. Conductivity, infrared, em., magnetic susceptibility and a complete structure determination on one of the compounds support a manganese(1v) formulation for the complexes.
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Journal Title
Australian Journal of Chemistry
Volume
27
Subject
Chemical sciences