dc.contributor.author | GOLDING, RM | |
dc.contributor.author | HEALY, PC | |
dc.contributor.author | COLOMBER, P | |
dc.contributor.author | WHITE, AH | |
dc.date.accessioned | 2017-05-03T11:08:58Z | |
dc.date.available | 2017-05-03T11:08:58Z | |
dc.date.issued | 1974 | |
dc.identifier.issn | 0004-9425 | |
dc.identifier.doi | 10.1071/CH9742089 | |
dc.identifier.uri | http://hdl.handle.net/10072/19541 | |
dc.description.abstract | The temperature dependence of the proton N.M.R. spectra of some simple tris(N,N-disubstituted dithiocarbamato)chromium(111) derivatives, [Cr(S2CNR2)3], has been studied in deuterochloroform solution over the range ? 60꠴o + 60ꃮ In these spectra, which are very broad, the N-CHn protons in certain cases exhibit a double peak unlike the iron(111) or manganese(111) complexes-probably a consequence of high energy barriers between the ? and ? enantiomers, the broadness of the spectra being ascribed to the lack of an appropriate relaxation mechanism. The spectra of a number of further iron(111) and manganese(111) derivatives are reported and the hyperfine coupling constants in the three series of complexes compared. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | CSIRO Publishing | |
dc.publisher.place | Australia | |
dc.relation.ispartofstudentpublication | N | |
dc.relation.ispartofpagefrom | 2089 | |
dc.relation.ispartofpageto | 2097 | |
dc.relation.ispartofjournal | Australian Journal of Chemistry | |
dc.relation.ispartofvolume | 27 | |
dc.rights.retention | Y | |
dc.subject.fieldofresearch | Chemical sciences | |
dc.subject.fieldofresearchcode | 34 | |
dc.title | N.M.R. studies of some chromium(III) dithiocarbamate complexes | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.date.issued | 2015-05-21T05:30:48Z | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |