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dc.contributor.authorGOLDING, RM
dc.contributor.authorHEALY, PC
dc.contributor.authorCOLOMBER, P
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:08:58Z
dc.date.available2017-05-03T11:08:58Z
dc.date.issued1974
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9742089
dc.identifier.urihttp://hdl.handle.net/10072/19541
dc.description.abstractThe temperature dependence of the proton N.M.R. spectra of some simple tris(N,N-disubstituted dithiocarbamato)chromium(111) derivatives, [Cr(S2CNR2)3], has been studied in deuterochloroform solution over the range ? 60꠴o + 60ꃮ In these spectra, which are very broad, the N-CHn protons in certain cases exhibit a double peak unlike the iron(111) or manganese(111) complexes-probably a consequence of high energy barriers between the ? and ? enantiomers, the broadness of the spectra being ascribed to the lack of an appropriate relaxation mechanism. The spectra of a number of further iron(111) and manganese(111) derivatives are reported and the hyperfine coupling constants in the three series of complexes compared.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherCSIRO Publishing
dc.publisher.placeAustralia
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom2089
dc.relation.ispartofpageto2097
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume27
dc.rights.retentionY
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.titleN.M.R. studies of some chromium(III) dithiocarbamate complexes
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:30:48Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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