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dc.contributor.authorColombera, P.en_US
dc.contributor.authorGolding, R.en_US
dc.contributor.authorHealy, P.en_US
dc.contributor.authorWhite, A.en_US
dc.date.accessioned2017-04-04T14:17:26Z
dc.date.available2017-04-04T14:17:26Z
dc.date.issued1974en_US
dc.identifier.issn00049425en_US
dc.identifier.doi10.1071/CH9742089en_US
dc.identifier.urihttp://hdl.handle.net/10072/19541
dc.description.abstractThe temperature dependence of the proton N.M.R. spectra of some simple tris(N,N-disubstituted dithiocarbamato)chromium(111) derivatives, [Cr(S2CNR2)3], has been studied in deuterochloroform solution over the range ? 60꠴o + 60ꃮ In these spectra, which are very broad, the N-CHn protons in certain cases exhibit a double peak unlike the iron(111) or manganese(111) complexes-probably a consequence of high energy barriers between the ? and ? enantiomers, the broadness of the spectra being ascribed to the lack of an appropriate relaxation mechanism. The spectra of a number of further iron(111) and manganese(111) derivatives are reported and the hyperfine coupling constants in the three series of complexes compared.en_US
dc.description.peerreviewedYesen_US
dc.description.publicationstatusYesen_US
dc.languageEnglishen_US
dc.language.isoen_US
dc.publisherCSIRO Publishingen_US
dc.publisher.placeAustraliaen_US
dc.relation.ispartofstudentpublicationNen_US
dc.relation.ispartofpagefrom2089en_US
dc.relation.ispartofpageto2097en_US
dc.relation.ispartofjournalAustralian Journal of Chemistryen_US
dc.relation.ispartofvolume27en_US
dc.rights.retentionYen_US
dc.subject.fieldofresearchcode250104en_US
dc.titleN.M.R. studies of some chromium(III) dithiocarbamate complexesen_US
dc.typeJournal articleen_US
dc.type.descriptionC1 - Peer Reviewed (HERDC)en_US
dc.type.codeC - Journal Articlesen_US
gro.date.issued2015-05-21T05:30:48Z
gro.hasfulltextNo Full Text


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