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dc.contributor.authorGOLDING, RM
dc.contributor.authorHEALY, P
dc.contributor.authorNEWMAN, P
dc.contributor.authorSINN, E
dc.contributor.authorTENNANT, WC
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:08:55Z
dc.date.available2017-05-03T11:08:55Z
dc.date.issued1970
dc.date.modified2008-09-26T01:13:20Z
dc.identifier.issn0021-9606
dc.identifier.doi10.1063/1.1673445
dc.identifier.urihttp://hdl.handle.net/10072/19563
dc.description.abstractThe NMR and magnetic susceptibility results of a series of manganese (III) dithiocarbamates have been determined and interpreted using a model where the d4 ion is in a crystal field of octahedral symmetry: the ground electronic state is the 5E state. The true symmetry about the metal ions in dithiocarbamates differs somewhat from octahedral, and the implications of this are discussed. By comparing the NMR results for the iron (III) dithiocarbamate analogs we have shown that the extent of d-electron delocalization depends markedly on the transition metal ion. The variation of the isotropic proton hyperfine interaction constants along the alkyl chain, which reflects the electronic configuration of these complexes, also depends markedly on the transition metal ion. 鱹70 American Institute of Physics
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherAmerican Institute of Physics
dc.publisher.placeUnited States
dc.publisher.urihttp://jcp.aip.org/
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom3105
dc.relation.ispartofpageto3109
dc.relation.ispartofissue6
dc.relation.ispartofjournalJournal of Chemical Physics
dc.relation.ispartofvolume52
dc.rights.retentionY
dc.subject.fieldofresearchPhysical sciences
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchEngineering
dc.subject.fieldofresearchcode51
dc.subject.fieldofresearchcode34
dc.subject.fieldofresearchcode40
dc.titleNMR and magnetic susceptibility measurements of a series of manganic dithiocarbamates
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued1970
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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