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dc.contributor.authorHealy, P.en_US
dc.contributor.authorWhite, A.en_US
dc.date.accessioned2017-05-03T11:08:57Z
dc.date.available2017-05-03T11:08:57Z
dc.date.issued1973en_US
dc.identifier.issn05848539en_US
dc.identifier.doi10.1016/0584-8539(73)80156-4en_US
dc.identifier.urihttp://hdl.handle.net/10072/19638
dc.description.abstractThe frequency of the V2i.r. active out-of-plane mode of the planar carbonate species in complexes of known crystal structure in a variety of coordination and site symmetry types varies between 820 and 880 cm-1. Within the context of the observed geometries and frequencies and an analysis of the motion of the CO3 system normal to the CO3 plane, the frequency is found to depend only on the variation in the force constant, the kinetic energy term being invariant. A tentative correlation with possible diagnostic applications is drawn between the ?2 frequency and site symmetry/coordination type.en_US
dc.description.peerreviewedYesen_US
dc.description.publicationstatusYesen_US
dc.languageEnglishen_US
dc.language.isoen_US
dc.publisherPergamon Pressen_US
dc.publisher.placeNetherlandsen_US
dc.relation.ispartofstudentpublicationNen_US
dc.relation.ispartofpagefrom1191en_US
dc.relation.ispartofpageto1195en_US
dc.relation.ispartofjournalSpectrochimica Acta Part A: Molecular Spectroscopyen_US
dc.relation.ispartofvolume29Aen_US
dc.rights.retentionYen_US
dc.subject.fieldofresearchcode250104en_US
dc.titleThe v2 vibration of the carbonate speciesen_US
dc.typeJournal articleen_US
dc.type.descriptionC1 - Peer Reviewed (HERDC)en_US
dc.type.codeC - Journal Articlesen_US
gro.date.issued2015-05-15T04:40:29Z
gro.hasfulltextNo Full Text


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