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dc.contributor.authorHEALY, PC
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:08:57Z
dc.date.available2017-05-03T11:08:57Z
dc.date.issued1973
dc.identifier.issn1386-1425
dc.identifier.doi10.1016/0584-8539(73)80156-4
dc.identifier.urihttp://hdl.handle.net/10072/19638
dc.description.abstractThe frequency of the V2i.r. active out-of-plane mode of the planar carbonate species in complexes of known crystal structure in a variety of coordination and site symmetry types varies between 820 and 880 cm-1. Within the context of the observed geometries and frequencies and an analysis of the motion of the CO3 system normal to the CO3 plane, the frequency is found to depend only on the variation in the force constant, the kinetic energy term being invariant. A tentative correlation with possible diagnostic applications is drawn between the ?2 frequency and site symmetry/coordination type.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherPergamon Press
dc.publisher.placeNetherlands
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom1191
dc.relation.ispartofpageto1195
dc.relation.ispartofjournalSpectrochimica Acta Part A: Molecular Spectroscopy
dc.relation.ispartofvolume29A
dc.rights.retentionY
dc.subject.fieldofresearchAnalytical chemistry
dc.subject.fieldofresearchMacromolecular and materials chemistry
dc.subject.fieldofresearchPhysical chemistry
dc.subject.fieldofresearchcode3401
dc.subject.fieldofresearchcode3403
dc.subject.fieldofresearchcode3406
dc.titleThe v2 vibration of the carbonate species
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-15T04:40:29Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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