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dc.contributor.authorHEALY, PC
dc.contributor.authorSKELTON, BW
dc.contributor.authorWATERS, AF
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:08:51Z
dc.date.available2017-05-03T11:08:51Z
dc.date.issued1991
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9911049
dc.identifier.urihttp://hdl.handle.net/10072/19927
dc.description.abstractAdducts (1 : 1) of copper(I) chloride, bromide and thiocyanate with quinoline have been synthesized and have been the subject of single-crystal X-ray structure determinations at 295 K. Crystals of the chloride are orthorhombic, P 212121, a 15.358(7), b 14.309(6), c 3.801(2)?, Z 4; R was 0.055 for 541 'observed' reflections. Crystals of the bromide are monoclinic, C2/c, a 19.417(5), b 14.048(4), c 15.753(6) ?, ߠ125.31(2)ଠZ 4 tetramers; R was 0.049 for 1138 'observed' reflections. Crystals of the thiocyanate are monoclinic, P 21/c, a 5.682(1), b 10.412(2), c 16.838(5)?, ߠ97.48(2)ଠZ 4 f.u .; R was 0.045 for 914 'observed' reflections. The chloride takes the form of the common 'stair' polymer, unexpectedly, while the thiocyanate is an expanded version of the same. The bromide provides a second example of a novel tetrameric 'basket' structure exemplified previously by the iodide analogue.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Vic.
dc.relation.ispartofpagefrom1049
dc.relation.ispartofpageto1059
dc.relation.ispartofissue8
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume44
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.titleLewis-base adducts of group 11 metal(I) compounds. LXII The crystal structures of the 1:1 adducts of copper(I) chloride, bromide and thiocyanate with quinoline
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-22T00:06:54Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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