dc.contributor.author | HEALY, PC | |
dc.contributor.author | SKELTON, BW | |
dc.contributor.author | WATERS, AF | |
dc.contributor.author | WHITE, AH | |
dc.date.accessioned | 2017-05-03T11:08:51Z | |
dc.date.available | 2017-05-03T11:08:51Z | |
dc.date.issued | 1991 | |
dc.identifier.issn | 0004-9425 | |
dc.identifier.doi | 10.1071/CH9911049 | |
dc.identifier.uri | http://hdl.handle.net/10072/19927 | |
dc.description.abstract | Adducts (1 : 1) of copper(I) chloride, bromide and thiocyanate with quinoline have been synthesized and have been the subject of single-crystal X-ray structure determinations at 295 K. Crystals of the chloride are orthorhombic, P 212121, a 15.358(7), b 14.309(6), c 3.801(2)?, Z 4; R was 0.055 for 541 'observed' reflections. Crystals of the bromide are monoclinic, C2/c, a 19.417(5), b 14.048(4), c 15.753(6) ?, ߠ125.31(2)ଠZ 4 tetramers; R was 0.049 for 1138 'observed' reflections. Crystals of the thiocyanate are monoclinic, P 21/c, a 5.682(1), b 10.412(2), c 16.838(5)?, ߠ97.48(2)ଠZ 4 f.u .; R was 0.045 for 914 'observed' reflections. The chloride takes the form of the common 'stair' polymer, unexpectedly, while the thiocyanate is an expanded version of the same. The bromide provides a second example of a novel tetrameric 'basket' structure exemplified previously by the iodide analogue. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | CSIRO Publishing | |
dc.publisher.place | Collingwood, Vic. | |
dc.relation.ispartofpagefrom | 1049 | |
dc.relation.ispartofpageto | 1059 | |
dc.relation.ispartofissue | 8 | |
dc.relation.ispartofjournal | Australian Journal of Chemistry | |
dc.relation.ispartofvolume | 44 | |
dc.subject.fieldofresearch | Chemical sciences | |
dc.subject.fieldofresearchcode | 34 | |
dc.title | Lewis-base adducts of group 11 metal(I) compounds. LXII The crystal structures of the 1:1 adducts of copper(I) chloride, bromide and thiocyanate with quinoline | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.date.issued | 2015-05-22T00:06:54Z | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |