Remarkable homology in the electronic spectra of the mixed-valence cation and anion radicals of a conjugated bis(porphyrinyl)butadiyne

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P. Arnold, Dennis
D. Hartnell, Regan
A. Heath, Graham
Newby, Leonora
D. Webster, Richard
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Hartnell, Regan D.
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2002
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Abstract

The pi-radical cation and anion of the dizinc complex of a bis(triarylporphyrinyl) butadiyne, 1(+) and 1(-), respectively, display remarkably similar near- IR signatures, with intense bands near 1000 and 2500 nm, as predicted by the appropriate frontier- orbital model for inter- porphyrin coupling across the conjugated bridge.

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Chemical Communications
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https://pubs.rsc.org/en/results?searchtext=Remarkable%20homology%20in%20the%20electronic%20spectra%20of%20the%20mixed-valence%20cation%20and%20anion%20radicals%20of%20a%20conjugated%20bis%28porphyrinyl%29butadiyne
DOI
10.1039/b200803n
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Chemical Sciences
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http://hdl.handle.net/10072/21512
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