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dc.contributor.authorLiu, Peng
dc.contributor.authorZhong, Kuan
dc.contributor.authorLiang, Chaolun
dc.contributor.authorYang, Qiqin
dc.contributor.authorTong, Yexiang
dc.contributor.authorLi, Gaoren
dc.contributor.authorHope, Greg A
dc.contributor.editorLeonard V Interrante
dc.date.accessioned2017-05-03T11:12:14Z
dc.date.available2017-05-03T11:12:14Z
dc.date.issued2008
dc.date.modified2010-11-04T07:06:07Z
dc.identifier.issn0897-4756
dc.identifier.doi10.1021/cm802225h
dc.identifier.urihttp://hdl.handle.net/10072/22522
dc.description.abstractThe 3D nanostructured antimony is synthesized by simply immerging an anodically oxidized copper sheet into SbCl3-(n-Bu)4NBF4-DMSO solution at room temperature. The morphology, shape, and structure were characterized by FE-SEM, XRD, and HRTEM. The 3D nanostructured antimony has a regular fourteen-faced polyhedron shape and is constructed by Sb nanowires. The Sb nanowires are single crystals with a rhombohedral crystal structure, the average diameter of the Sb nanowires ranges from 5 to 8 nm. The HRTEM investigation and theoretical calculations indicate that Sb nanowires grow along the arrises of its rhombohedral lattice. The growth mechanism is proposed, the electron transport along Sb nanowires may be anisotropic and results in the preferred orientation of the Sb nanowires growth. The nanocages can be formed by quaric self-assembly of Sb nanowires because of the anisotropy of its rhombohedral crystal structure.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoen_AU
dc.publisherAmerican Chemical Society
dc.publisher.placeUnited States
dc.publisher.urihttp://pubs.acs.org/journal/cmatex
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom7532
dc.relation.ispartofpageto7538
dc.relation.ispartofissue24
dc.relation.ispartofjournalChemistry of Materials
dc.relation.ispartofvolume20
dc.rights.retentionY
dc.subject.fieldofresearchNanochemistry and Supramolecular Chemistry
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchEngineering
dc.subject.fieldofresearchcode030302
dc.subject.fieldofresearchcode03
dc.subject.fieldofresearchcode09
dc.titleSelf-assembly of three-dimensional nanostructured antimony
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.rights.copyright© 2008 American Chemical Society. Self-archiving of the author-manuscript version is not yet supported by this publisher. Please refer to the journal link for access to the definitive, published version or contact the authors for more information.
gro.date.issued2008
gro.hasfulltextNo Full Text
gro.griffith.authorHope, Gregory A.


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