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dc.contributor.authorBARRON, PF
dc.contributor.authorDYASON, JC
dc.contributor.authorENGELHARDT, LM
dc.contributor.authorHEALY, PC
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:28Z
dc.date.available2017-05-03T11:09:28Z
dc.date.issued1984
dc.date.modified2009-06-12T06:34:16Z
dc.identifier.issn0020-1669
dc.identifier.doi10.1021/ic00191a020
dc.identifier.urihttp://hdl.handle.net/10072/24229
dc.description.abstractCrystal structure analysis of the tetrameric 1:l adduct of PPh3 with CuBr, [CuBrPPhpl4, recrystallized from refluxing toluene, shows that it has crystallized in a 'cubane" rather than the previously recorded "step" form. A residual of 0.044 was obtained for 3708 independent observed diffractometer reflections recorded at 295 K after full-matrix least-squares refinement; crystals are isomorphous with the chloride, with an orthorhombic Pbcn cell, a = 17.662 ( 5 ) A, b = 20.748 (7) A, c = 18.351 (6) A, and Z(tetramer) = 4. The existence of the cubane form of the bromide was discovered during high-resolution solid-state 31P NMR spectral studies on a series of cuprous halide-triphenylphosphine complexes.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.publisher.placeUnited States
dc.publisher.urihttp://pubs.acs.org/journal/inocaj
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom3766
dc.relation.ispartofpageto3769
dc.relation.ispartofjournalInorganic Chemistry
dc.relation.ispartofvolume23
dc.rights.retentionY
dc.subject.fieldofresearchInorganic chemistry
dc.subject.fieldofresearchPhysical chemistry
dc.subject.fieldofresearchOther chemical sciences
dc.subject.fieldofresearchcode3402
dc.subject.fieldofresearchcode3406
dc.subject.fieldofresearchcode3499
dc.titleLewis Base Adducts of Group 1B Metal(I) Compounds. 8. High-resolution solid-state 31P nuclear magnetic resonance spectra of tetrameric (triphenylphosphine)copper(I) halide complexes and crystal structure determination of cubane [PPh3CuBr]4
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.rights.copyright© 1984 American Chemical Society. Self-archiving of the author-manuscript version is not yet supported by this publisher. The contents of this journal can be freely accessed online via the ACS web page 12 months after publication. Use hypertext link above to access the ACS website.
gro.date.issued1984
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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