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dc.contributor.authorBARRON, PF
dc.contributor.authorDYASON, JC
dc.contributor.authorHEALY, PC
dc.contributor.authorENGELHARDT, LM
dc.contributor.authorSKELTON, BW
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:19Z
dc.date.available2017-05-03T11:09:19Z
dc.date.issued1986
dc.date.modified2009-08-21T06:38:38Z
dc.identifier.issn0300-9246
dc.identifier.doi10.1039/DT9860001965
dc.identifier.urihttp://hdl.handle.net/10072/24241
dc.description.abstractSolid-state cross-polarization magic angle spinning 31P n.m.r. spectroscopy, single-crystal X-ray structure determination, and i.r. spectroscopy have been used to investigate the properties of the adducts of triphenylphosphine with silver(1) nitrate: Ag( PPh,) NO,, (1); Ag( PPh,),NO,, (2); Ag( PPh,),NO,, (3); and Ag( PPh,),NO,, (4). The value of 'J(Ag-P) decreases with increasing co-ordination number: (1 ), 780; (2), 470; (3), 31 0; and (4), 190 Hz, paralleling solution results. Single-crystal X-ray structure determinations of compounds (2)-(4) have been performed: (2), triclinic, space group P i , a = 11.821 (3), b = 11.990(3), c = 13.660(3) A, u = 102.05(2), p = 11 2.80(2), and y = 105.30(2)", yielding R = 0.036 for 4 090 'observed' reflections; Ag-P 2.443(1) and 2.440(1) A, P-Ag-P 138.21 (5)"; (3), monoclinic, space group P2,/n, a = 18.984(5), b = 13.71 0(3), c = 17.900(4) A, and p = 94.94(2)", yielding R = 0.053 for 5 126 reflections; Ag-P 2.630(2), 2.525(1), and 2.545 2) A, P-Ag-P 11 8.37(5), 11 2.07(4), and 11 6.44(5)"; (4), trigonal, space group R3, a = 19.07(2) A , and u = 43.77(5)", yielding R = 0.060 for 1 903 observed reflections; Ag-P 2.643(3) and 2.671 (4) A, P-Ag-P 109.49(12) and 109.45(10)". Structures (2) and (3) [and (l)] are isomorphous with the analogous triphenylarsine compounds. In all cases the nitrate group is only weakly co-ordinated [and is ionic in (4) 3: Ag-0 2.464(4) and 2.649(4) in (2), 2.684(6) and 2.775(6) A in (3). These weak interactions are reflected in the small splitting observed for the asymmetric N-0 stretching vibrational mode compared to the analogous copper( I) compounds.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.format.extent816353 bytes
dc.format.mimetypeapplication/pdf
dc.languageEnglish
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.publisher.placeUnited Kingdom
dc.publisher.urihttp://www.rsc.org/Publishing/Journals/dt/
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom1965
dc.relation.ispartofpageto1970
dc.relation.ispartofjournalJournal of the Chemical Society, Dalton Transactions
dc.relation.ispartofvolume1986
dc.rights.retentionY
dc.subject.fieldofresearchInorganic Chemistry
dc.subject.fieldofresearchOther Chemical Sciences
dc.subject.fieldofresearchTheoretical and Computational Chemistry
dc.subject.fieldofresearchcode0302
dc.subject.fieldofresearchcode0399
dc.subject.fieldofresearchcode0307
dc.titleLewis Base Adducts of Group 11 Metal Compounds. part 24. Co-ordination of triphenylphosphine with silver nitrate. A solid-state cross-polarization magic angle spinning 31P nuclear magnetic resonance, crystal structure, and infrared spectroscopic study of
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.rights.copyright© 1986 Royal Society of Chemistry. This is the author-manuscript version of the paper. Reproduced in accordance with the copyright policy of the publisher.
gro.date.issued1986
gro.hasfulltextFull Text
gro.griffith.authorHealy, Peter C.


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