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dc.contributor.authorBOWMAKER, GA
dc.contributor.authorDYASON, JC
dc.contributor.authorHEALY, PC
dc.contributor.authorENGELHARDT, LM
dc.contributor.authorPAKAWATCHAI, C
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:16Z
dc.date.available2017-05-03T11:09:16Z
dc.date.issued1987
dc.date.modified2009-08-21T06:39:28Z
dc.identifier.issn0300-9246
dc.identifier.doi10.1039/DT9870001089
dc.identifier.urihttp://hdl.handle.net/10072/24259
dc.description.abstractSingle - crystal X-ray diffract ion structure determi nations, high resolution solid -state crosspolarization magic-angle spinning 31P n.m.r., and far4.r. spectral data are reported for the mononuclear 2 : 1 adducts of triphenylphosphine with copper( I) and gold( I) halides, [ M (PPh,),X] . Crystal data are reported for [Cu( PPh,),CI]-0.5C6H6, [Cu( PPh,),l], [Au( PPh,),CI] (unsolvated), [Au(PPh,),Br], and [Au(PPh,),l]. In each structure the PPh, ligands adopt an eclipsed conformation about M-P with respect to M-X, with X-M-P-C(11) conformational angles ranging from 0.5 to 18.3". Within each halide series, M-P distances and P-M-P angles are independent of halogen [CuCI: 2.272(2), 2.260(2) A, 125.48(7)"; Cul: 2.273(2) A, 126.9(1)"; AuCl (unsolvated): 2.336(4), 2.31 7(4) A, 135.7(1); AuBr: 2.323(2) A, 132.45(8)"; and Aul: 2.333(2) A, 132.1 3(7)"]. Considerable asymmetry (490-560 Hz) in the solid-state 31P n.m.r. quartets obtained for M = Cu reflects the lower symmetry of the copper environment relative to four-co-ordinate tetrahedral compounds. Solid-state 31P chemical shift data for M = Au are independent of halogen (CI, 37; Br, 38; I, 36 p.p.m.). The far4.r. spectrum of [Cu( PPh,),l] reveals a strong band at 184 cm-l which is assigned to the Cul terminal stretching mode.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.format.extent960160 bytes
dc.format.extent40409 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.languageEnglish
dc.language.isoen_AU
dc.publisherRoyal Society of Chemistry
dc.publisher.placeUnited Kingdom
dc.publisher.urihttp://www.rsc.org/Publishing/Journals/dt/
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom1089
dc.relation.ispartofpageto1097
dc.relation.ispartofissue5
dc.relation.ispartofjournalJournal of the Chemical Society, Dalton Transactions
dc.relation.ispartofvolume1987
dc.rights.retentionY
dc.subject.fieldofresearchInorganic Chemistry
dc.subject.fieldofresearchOther Chemical Sciences
dc.subject.fieldofresearchTheoretical and Computational Chemistry
dc.subject.fieldofresearchcode0302
dc.subject.fieldofresearchcode0399
dc.subject.fieldofresearchcode0307
dc.titleLewis-base adducts of Group 11 metal(I) compounds. Part 27. Solid-state phosphorus-31 cross-polarization magic-angle spinning nuclear magnetic resonance, far-infrared, and structural studies on the mononuclear 2 : 1 adducts of triphenylphosphine with cop
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.rights.copyright© 1987 Royal Society of Chemistry. This is the author-manuscript version of the paper. Reproduced in accordance with the copyright policy of the publisher.
gro.date.issued1987
gro.hasfulltextFull Text
gro.griffith.authorHealy, Peter C.
gro.griffith.authorDyason, Jeffrey C.


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