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dc.contributor.authorSmith, Graham
dc.contributor.authorWermuth, Urs D
dc.contributor.authorHealy, Peter C
dc.date.accessioned2017-05-03T11:08:59Z
dc.date.available2017-05-03T11:08:59Z
dc.date.issued2007
dc.date.modified2009-08-06T06:04:45Z
dc.identifier.issn1600-5368
dc.identifier.doi10.1107/S1600536807056930
dc.identifier.urihttp://hdl.handle.net/10072/24981
dc.description.abstractThe polymeric structure of the title compound, poly[[diaquabis([mu]-biphenyl-4,4'-disulfonato)tetrapotassium(I)] dihydrate], {[K2(C12H8O6S2)(H2O)]爲O}n, is based on an asymmetric unit comprising three independent and different potassium centres, one six-coordinate [K-O = 2.657 (3)-2.866 (5) ŝ, one seven-coordinate [K-O = 2.703 (3)-3.040 (4) ŝ, and the third ten-coordinate [K-O = 2.751 (3)-3.079 (4) ŝ, with two of these lying on crystallographic mirror planes. The four half-occupancy water molecules also lie on the mirror planes with two coordinated (one monodentate, the other bidentate bridging) and two as molecules of solvation. The interlinked coordination polyhedra form chains which are joined laterally through the biphenyl residues as well as through head-to-tail water hydrogen-bonding interactions, giving a two-dimensional structure.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.format.extent478681 bytes
dc.format.mimetypeapplication/pdf
dc.languageEnglish
dc.language.isoen_AU
dc.publisherBlackwell Munksgaard
dc.publisher.placeCopenhagen, Denmark
dc.publisher.urihttp://journals.iucr.org/e/journalhomepage.html
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefromM3056
dc.relation.ispartofpagetoM3057
dc.relation.ispartofjournalActa Crystallographica. Section E: Structure reports online
dc.relation.ispartofvolumeE63
dc.rights.retentionY
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchcode03
dc.titleDipotassium biphenyl-4,4'-disulfonate dihydrate: a coordination polymer
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
dcterms.licensehttp://creativecommons.org/licenses/by/2.0/uk/legalcode.
gro.rights.copyright© The Author(s) 2007. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode.
gro.date.issued2007
gro.hasfulltextFull Text
gro.griffith.authorHealy, Peter C.
gro.griffith.authorWermuth, Urs D.


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