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dc.contributor.authorHEALY, PC
dc.contributor.authorKILDEA, JD
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:01Z
dc.date.available2017-05-03T11:09:01Z
dc.date.issued1989
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9890137
dc.identifier.urihttp://hdl.handle.net/10072/24982
dc.description.abstractA complete array of [LcuX2CuL] dimers for the system CuX/monodentate nitrogen base, L, all X = Cl, Br, I, has been synthesized and structurally characterized for the highly hindered pyridine base L 蠱,2,3,4,5,6,7,8-octahydroacridine, enabling comparison of stereochemical parameters with previously characterized [L2CuX2CuL2] arrays (L monodentate ). With L-2,2,6,6-tetramethylpiperidine, a similar dimer is also obtained with copper(I) iodide, but with the chloride and bromide adducts linear monomers [ LCuX ] have been obtained, the first to be structurally characterized for the copper(I) halide/nitrogen base system. In the latter Cu-Cl, Br are 2.087(2) and 2.216(2), 2.202(2) A, Cu-N being 1.923(3) and 1.931(9), 1.9337) Š.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoen_US
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Vic.
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom137
dc.relation.ispartofpageto148
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume42
dc.rights.retentionY
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchcode03
dc.titleLewis-base adducts of group 11 metal(I) compounds. XLIV : Synthesis and conformational systematics of 1:1 copper(I) halide/nitrogen-base adducts as [(N-base)CuX2Cu(N-base)] dimers (X = Cl, Br, I) and [(N-base)CuX] monomers (X = Cl, Br)
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:24:45Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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