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dc.contributor.authorENGELHARDT, LM
dc.contributor.authorHEALY, PC
dc.contributor.authorKILDEA, JD
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:02Z
dc.date.available2017-05-03T11:09:02Z
dc.date.issued1989
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9890895
dc.identifier.urihttp://hdl.handle.net/10072/24985
dc.description.abstractComplexes [ XCu ( py )(PPh3)2], X = Cl, Br, I, py = pyridine, have been synthesized and characterized by single-crystal X-ray structure determination. Chloride and iodide derivatives have similar cells [ isomorphous (?) but not isostructural ], triclinic, pi, a = 19.5 A, b = 10.5, c = 9.6 Š, a 蠶6, ߠ蠸6, ? 蠸3ꬠZ = 2; the bromide is monoclinic, Cc, a 13.568(9), b 15.760(12), c 16.545(8) Š, ߠ95.65(5)ꬠZ = 4. Cl, Br, I structures were refined to residuals of 0.042, 0.055, 0.039 for 4288, 2241, 4808 'observed' reflections. In all cases, the copper atom is four-coordinate; for such an array, Cu-X lengths are unusually short [2.318(2), 2.459(2), 2.636(1) Š(Cl, Br, I) and Cu-N unusually long (2.14(1) Š], while (Cu-P) increase from 2.264 to 2.288 Šacross the series. The dominant aspect of the complexes is thus that of XCu (PPh3)2 solvated by pyridine.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Vic.
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom895
dc.relation.ispartofpageto905
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume42
dc.rights.retentionY
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.titleLewis-base adducts of group 11 metal(I) compounds. LI : Synthesis and structural characterization of mononuclear chloro-, bromo- and iodo-pyridinebis(triphenylphosphine)copper(I) complexes
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:25:04Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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