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dc.contributor.authorENGELHARDT, LM
dc.contributor.authorHEALY, PC
dc.contributor.authorKILDEA, JD
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:02Z
dc.date.available2017-05-03T11:09:02Z
dc.date.issued1989
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9890895
dc.identifier.urihttp://hdl.handle.net/10072/24985
dc.description.abstractComplexes [ XCu ( py )(PPh3)2], X = Cl, Br, I, py = pyridine, have been synthesized and characterized by single-crystal X-ray structure determination. Chloride and iodide derivatives have similar cells [ isomorphous (?) but not isostructural ], triclinic, pi, a = 19.5 A, b = 10.5, c = 9.6 Š, a 蠶6, ߠ蠸6, ? 蠸3ꬠZ = 2; the bromide is monoclinic, Cc, a 13.568(9), b 15.760(12), c 16.545(8) Š, ߠ95.65(5)ꬠZ = 4. Cl, Br, I structures were refined to residuals of 0.042, 0.055, 0.039 for 4288, 2241, 4808 'observed' reflections. In all cases, the copper atom is four-coordinate; for such an array, Cu-X lengths are unusually short [2.318(2), 2.459(2), 2.636(1) Š(Cl, Br, I) and Cu-N unusually long (2.14(1) Š], while (Cu-P) increase from 2.264 to 2.288 Šacross the series. The dominant aspect of the complexes is thus that of XCu (PPh3)2 solvated by pyridine.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoen_US
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Vic.
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom895
dc.relation.ispartofpageto905
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume42
dc.rights.retentionY
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchcode03
dc.titleLewis-base adducts of group 11 metal(I) compounds. LI : Synthesis and structural characterization of mononuclear chloro-, bromo- and iodo-pyridinebis(triphenylphosphine)copper(I) complexes
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:25:04Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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