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dc.contributor.authorENGELHARDT, LM
dc.contributor.authorHEALY, PC
dc.contributor.authorKILDEA, JD
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:03Z
dc.date.available2017-05-03T11:09:03Z
dc.date.issued1989
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9890907
dc.identifier.urihttp://hdl.handle.net/10072/24986
dc.description.abstractThe mononuclear adducts chloro - and bromo-pyridinebis (triphenylphosphine)silver have been synthesized and structurally characterized by single-crystal X-ray diffraction methods. The two complexes are isomorphous, monoclinic, space group P21 or P21/m, a 蠹.8, b 蠲0.0, c 蠹.1 Š, ߠ蠹7.5ꬠZ 2; in space group P21/m, they were refined to residuals of 0.038, 0.036 for 2392, 2157 'observed' reflections respectively. No comparable iodide adduct has been isolated. In both structures the silver atom is four-coordinate; Ag-Cl,Br are 2.511(2), 2.629(1) Ż Ag-P, 2.472(1), 2.476(1) Ŭ and Ag-N, 2.585(5), 2.570(5) Šrespectively, the Ag-N distance being longer than Ag-P, indicating very weak coordination of the pyridine.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoen_US
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Vic.
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom907
dc.relation.ispartofpageto912
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume42
dc.rights.retentionY
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchcode03
dc.titleLewis-base adducts of group 11 metal(I) compounds. LII : Synthesis and structural characterization of mononuclear chloro- and bromo-pyridinebis(triphenylphosphine)silver(I) complexes
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:25:19Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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