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dc.contributor.authorEngelhardt, Lutz M.en_US
dc.contributor.authorHealy, Peteren_US
dc.contributor.authorD. Kildea, Johnen_US
dc.contributor.authorH. White, Allanen_US
dc.date.accessioned2017-05-03T11:09:03Z
dc.date.available2017-05-03T11:09:03Z
dc.date.issued1989en_US
dc.identifier.issn00049425en_US
dc.identifier.doi10.1071/CH9890907en_US
dc.identifier.urihttp://hdl.handle.net/10072/24986
dc.description.abstractThe mononuclear adducts chloro - and bromo-pyridinebis (triphenylphosphine)silver have been synthesized and structurally characterized by single-crystal X-ray diffraction methods. The two complexes are isomorphous, monoclinic, space group P21 or P21/m, a 蠹.8, b 蠲0.0, c 蠹.1 Š, ߠ蠹7.5ꬠZ 2; in space group P21/m, they were refined to residuals of 0.038, 0.036 for 2392, 2157 'observed' reflections respectively. No comparable iodide adduct has been isolated. In both structures the silver atom is four-coordinate; Ag-Cl,Br are 2.511(2), 2.629(1) Ż Ag-P, 2.472(1), 2.476(1) Ŭ and Ag-N, 2.585(5), 2.570(5) Šrespectively, the Ag-N distance being longer than Ag-P, indicating very weak coordination of the pyridine.en_US
dc.description.peerreviewedYesen_US
dc.description.publicationstatusYesen_US
dc.languageEnglishen_US
dc.language.isoen_US
dc.publisherCSIRO Publishingen_US
dc.publisher.placeCollingwood, Vic.en_US
dc.relation.ispartofstudentpublicationNen_US
dc.relation.ispartofpagefrom907en_US
dc.relation.ispartofpageto912en_US
dc.relation.ispartofjournalAustralian Journal of Chemistryen_US
dc.relation.ispartofvolume42en_US
dc.rights.retentionYen_US
dc.subject.fieldofresearchcode250105en_US
dc.titleLewis-base adducts of group 11 metal(I) compounds. LII : Synthesis and structural characterization of mononuclear chloro- and bromo-pyridinebis(triphenylphosphine)silver(I) complexesen_US
dc.typeJournal articleen_US
dc.type.descriptionC1 - Peer Reviewed (HERDC)en_US
dc.type.codeC - Journal Articlesen_US
gro.date.issued2015-05-21T05:25:19Z
gro.hasfulltextNo Full Text


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