dc.contributor.author | BOWMAKER, GA | |
dc.contributor.author | HEALY, PC | |
dc.date.accessioned | 2017-05-03T11:09:14Z | |
dc.date.available | 2017-05-03T11:09:14Z | |
dc.date.issued | 1988 | |
dc.date.modified | 2009-08-06T06:05:25Z | |
dc.identifier.issn | 0584-8539 | |
dc.identifier.doi | 10.1016/0584-8539(88)80267-8 | |
dc.identifier.uri | http://hdl.handle.net/10072/24992 | |
dc.description.abstract | The far i.r. spectra of "cubane" [Ph3PCuCl]4, [Ph3PCuBr]4, and [Ph3PCuI]4, and "step" [Ph3PCuBr]4, and [Ph3PCuI]4, have been measured at ca 298 K and ca 125 K. The spectra of the "cubane" structures show two strong T2?(CuX) bands at: 160 and 180 cm- for the chloride, 119 and 144 cm- for the bromide and 100 and 140 cm- for the iodide, with resolution increasing along the sequence Cl < Br < I. The spectra of the "step" structures were virtually identical with previously reported data, with doubly and triply bridged ?(CuX) being observed at: 135 cm- and 174 cm- for the bromide, and 109 and 162 cm- for the iodide. The far i.r. spectra of [Et3PCuX]4, [Et3NCuX]4 (X = Cl, Br), [Et3N]3[CuI]4 and [Et3NAgI]4, all of which contain a "cubane" M4X4 core, have also been measured. Band assignments are supported by a normal coordinate calculation for isolated Td Cu4X4 units. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | Pergamon Journals Ltd. | |
dc.publisher.place | Netherlands | |
dc.publisher.uri | http://www.sciencedirect.com/science/journal/05848539 | |
dc.relation.ispartofstudentpublication | N | |
dc.relation.ispartofpagefrom | 115 | |
dc.relation.ispartofpageto | 119 | |
dc.relation.ispartofissue | 1 | |
dc.relation.ispartofjournal | Spectrochimica Acta Part A: Molecular Spectroscopy | |
dc.relation.ispartofvolume | 44 | |
dc.rights.retention | Y | |
dc.subject.fieldofresearchcode | 250104 | |
dc.title | The characterization of tetrameric complexes of copper(I) halides with phosphine and amine ligands by far infrared spectroscopy | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.rights.copyright | © 1988 Elsevier. Please refer to the journal's website for access to the definitive, published version. | |
gro.date.issued | 1988 | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |