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dc.contributor.authorHEALY, PC
dc.contributor.authorMILLS, NK
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:29Z
dc.date.available2017-05-03T11:09:29Z
dc.date.issued1983
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9831851
dc.identifier.urihttp://hdl.handle.net/10072/24996
dc.description.abstractThe crystal structures of the title compounds have been determined at 295(1) K by single-crystal X-ray diffraction methods. For [AgI(Et3N)] (1), the unit cell is tetragonal, P42/nmc, a 13.202(6),c 11.654(8) Ż the structure was refined to a residual of 0.077 for 589 independent 'observed' reflections, and is isostructural with the 'pseudo-cubane' triethylphosphine and triethylarsineanalogues with two tetrameric units in the cell. For [AgI(2-MeC5H4N)] (2), the cell is orthorhombic,P212121, a 16.63(1), b 10.797(9), c 4.570(4) Ŭ Z 4; a residual of 0.030 was obtained for 770 independent 'observed' reflections. For [AgI(3-MeC5H4N)] (3), the cell is monoclinic, P21/n, a 19.57(2), b 4.633(3), c 9.355(7) Ŭ ߠ90.85(7)ꬠZ 4, a residual of 0.038 being obtained for 1382 independent 'observed' reflections. For [AgI(C9H7N)](4), the unit cell is monoclinic, P21/n, a 12.964(9), b 16.84(2), c 4.454(4) Ŭ ߠ97.10(7)ꬠZ 4, a residual of 0.040 being obtained for 660 'observed' independent reflections. For compounds (2)-(4), the observed structures are all 'stairpolymers'; the structures of (2) and (3) are quite similar, but that of (4) exhibits significant differences.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoen_US
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Australia
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom1851
dc.relation.ispartofpageto1864
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume36
dc.rights.retentionY
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchcode03
dc.titleLewis-Base adducts of Group 1 Metal(I) Compounds. III : Synthesis and crystal structures of the 1 : 1 adducts of silver(I) iodide with triethylamine, 2- and 3-methylpyridine and quinoline
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:26:06Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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