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dc.contributor.authorHEALY, PC
dc.contributor.authorPATRICK, JM
dc.contributor.authorSKELTON, BW
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:29Z
dc.date.available2017-05-03T11:09:29Z
dc.date.issued1983
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9832031
dc.identifier.urihttp://hdl.handle.net/10072/24997
dc.description.abstractThe crystal structures of three iron complexes [FeCI3(phen)(MeOH)].MeOH (I), [FeCl3(phen)(H2O)] (2) and [phenH]+ [FeCl4(phen)]- (3) have been determined by single-crystal X-ray diffraction methods at 295(1) K, and refined by least squares to residuals of 0.044 (1600 'observed' reflections), 0.040 (806) and 0.050 (2496), respectively. Crystals of (1) are monoclinic, P21/c, a 8.005(9), b 14.805(11), c 14.830(12) A, P 101.03(7)ଠZ 4; for (2), triclinic, space group P1 , a 10.591(8), b 10.227(7), c 6.613(3) ?, a 108.21(5), ߠ100.69(5), ? 91.98(6)ಬ 2 ; for (3), triclinic, P1, a 18.560(8), b 10.302(5), c 6.981(3) ?, a 106.79(4), ߠ94.50(4), ? 103.15(4)ଠZ 2. In all structures, the iron atoms are six-coordinate, with the disposition of the three chlorine atoms being fac in (1) and (2).
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoen_US
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Australia
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom2031
dc.relation.ispartofpageto2041
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume36
dc.rights.retentionY
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchcode03
dc.titleStructural studies in the iron(III)/chloride/α,α'-diimine system. I : The six-coordinate mononuclear fac-[FeCl3(phen)X] system, X = MeOH, H2O, Cl-
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:26:11Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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