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dc.contributor.authorHEALY, PC
dc.contributor.authorKILDEA, JD
dc.contributor.authorSKELTON, BW
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:08:59Z
dc.date.available2017-05-03T11:08:59Z
dc.date.issued1989
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9890079
dc.identifier.urihttp://hdl.handle.net/10072/24999
dc.description.abstractThe structural chemistry of the polymeric 1:1 adducts of copper(1) halides ( CuX ; X = Cl, Br, I) with nitrile bases (exemplified by aceto- and benzo-nitrile ) has been systematically explored. Single-crystal X-ray structure redeterminations of enhanced precision have been carried out for all acetonitrile adducts (refined as orthorhombic, Pbnm , Z 4, a 蠱3.0, b 蠸.5, c 蠴.0 Š; R 0.039, 0.030, 0.043 for No = 534, 365, 727 'observed' reflections) and the chloride and bromide benzonitrile adducts (monoclinic, P21/n, a 蠳.9, b 蠱7.5, c 豰.9 Š, ߠ蠹8, Z 4); R 0.046, 0.048 for No = 1452, 1209); all structures are of the common one-dimensional 'stair' polymer type. In these adducts, the ligand is essentially 'one-dimensional' with substituents well removed from the point of attachment and from interaction within the parent polymer chain. Under these circumstances, the polymer is essentially 'orthogonal' with Cu-X crosslinks at (or nearly at) right angles to the polymer axis, and containing quasi-mirror planes, the series providing reference parameters for the description of distortions observed in these polymers when more hindered bases are coordinated.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Vic.
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom79
dc.relation.ispartofpageto91
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume42
dc.rights.retentionY
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.titleLewis-Base Adducts of Group 11 Metal(I) Compounds. XL : Conformational systematics of [(N-base)1(CuX)1]∞ orthogonal 'stair' polymers (N-base = 'one-dimensional' aceto-, benzo-nitrile ligand)
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:26:35Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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