dc.contributor.author | HEALY, PC | |
dc.contributor.author | KILDEA, JD | |
dc.contributor.author | SKELTON, BW | |
dc.contributor.author | WHITE, AH | |
dc.date.accessioned | 2017-05-03T11:08:59Z | |
dc.date.available | 2017-05-03T11:08:59Z | |
dc.date.issued | 1989 | |
dc.identifier.issn | 0004-9425 | |
dc.identifier.doi | 10.1071/CH9890079 | |
dc.identifier.uri | http://hdl.handle.net/10072/24999 | |
dc.description.abstract | The structural chemistry of the polymeric 1:1 adducts of copper(1) halides ( CuX ; X = Cl, Br, I) with nitrile bases (exemplified by aceto- and benzo-nitrile ) has been systematically explored. Single-crystal X-ray structure redeterminations of enhanced precision have been carried out for all acetonitrile adducts (refined as orthorhombic, Pbnm , Z 4, a 蠱3.0, b 蠸.5, c 蠴.0 Š; R 0.039, 0.030, 0.043 for No = 534, 365, 727 'observed' reflections) and the chloride and bromide benzonitrile adducts (monoclinic, P21/n, a 蠳.9, b 蠱7.5, c 豰.9 Š, ߠ蠹8, Z 4); R 0.046, 0.048 for No = 1452, 1209); all structures are of the common one-dimensional 'stair' polymer type. In these adducts, the ligand is essentially 'one-dimensional' with substituents well removed from the point of attachment and from interaction within the parent polymer chain. Under these circumstances, the polymer is essentially 'orthogonal' with Cu-X crosslinks at (or nearly at) right angles to the polymer axis, and containing quasi-mirror planes, the series providing reference parameters for the description of distortions observed in these polymers when more hindered bases are coordinated. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | CSIRO Publishing | |
dc.publisher.place | Collingwood, Vic. | |
dc.relation.ispartofstudentpublication | N | |
dc.relation.ispartofpagefrom | 79 | |
dc.relation.ispartofpageto | 91 | |
dc.relation.ispartofjournal | Australian Journal of Chemistry | |
dc.relation.ispartofvolume | 42 | |
dc.rights.retention | Y | |
dc.subject.fieldofresearch | Chemical sciences | |
dc.subject.fieldofresearchcode | 34 | |
dc.title | Lewis-Base Adducts of Group 11 Metal(I) Compounds. XL : Conformational systematics of [(N-base)1(CuX)1]∞ orthogonal 'stair' polymers (N-base = 'one-dimensional' aceto-, benzo-nitrile ligand) | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.date.issued | 2015-05-21T05:26:35Z | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |