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  • Lewis-Base Adducts of Group 11 Metal(I) Compounds. XLIII : Synthesis and structural systematics of 1:1 copper(I) halide/nitrogen base adducts as [(N-base)1(CuX)1]∞ 'split-stair' polymers (X = Cl, Br, I; N-base = acridine, quinaldine and 2,6-dimethyl- a

    Author(s)
    HEALY, PC
    KILDEA, JD
    SKELTON, BW
    WHITE, AH
    Griffith University Author(s)
    Healy, Peter C.
    Year published
    1989
    Metadata
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    Abstract
    The complete array of single strand ('split-stair') polymers for the 1 : 1 system CuX/monodentate nitrogen base, L, all X= Cl, Br, I, has now been synthesized and structurally characterized by using the highly hindered pyridine bases, L= acridine and quinaldine . Similar polymers, [ LCuX ] 8, are also obtained with L = 2,6-dimethylpyridine for X = Cl, Br (but not I which is a dimer , [LCuI2CuL]), and for L = 2,4,6- trimethylpyridine, X = Br, I (but not Cl, which is ionic [CuL2]+[CuCl2]-). A general feature of all polymeric structures, although diverse in space group and not isomorphous in respect of polymer disposition, is ...
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    The complete array of single strand ('split-stair') polymers for the 1 : 1 system CuX/monodentate nitrogen base, L, all X= Cl, Br, I, has now been synthesized and structurally characterized by using the highly hindered pyridine bases, L= acridine and quinaldine . Similar polymers, [ LCuX ] 8, are also obtained with L = 2,6-dimethylpyridine for X = Cl, Br (but not I which is a dimer , [LCuI2CuL]), and for L = 2,4,6- trimethylpyridine, X = Br, I (but not Cl, which is ionic [CuL2]+[CuCl2]-). A general feature of all polymeric structures, although diverse in space group and not isomorphous in respect of polymer disposition, is the presence of a short crystallographic axis (about 4 Š) as the unit translational repeat distance.
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    Journal Title
    Australian Journal of Chemistry
    Volume
    42
    DOI
    https://doi.org/10.1071/CH9890115
    Subject
    Chemical sciences
    Publication URI
    http://hdl.handle.net/10072/25000
    Collection
    • Journal articles

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