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dc.contributor.authorHEALY, PC
dc.contributor.authorKILDEA, JD
dc.contributor.authorSKELTON, BW
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:01Z
dc.date.available2017-05-03T11:09:01Z
dc.date.issued1989
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9890115
dc.identifier.urihttp://hdl.handle.net/10072/25000
dc.description.abstractThe complete array of single strand ('split-stair') polymers for the 1 : 1 system CuX/monodentate nitrogen base, L, all X= Cl, Br, I, has now been synthesized and structurally characterized by using the highly hindered pyridine bases, L= acridine and quinaldine . Similar polymers, [ LCuX ] 8, are also obtained with L = 2,6-dimethylpyridine for X = Cl, Br (but not I which is a dimer , [LCuI2CuL]), and for L = 2,4,6- trimethylpyridine, X = Br, I (but not Cl, which is ionic [CuL2]+[CuCl2]-). A general feature of all polymeric structures, although diverse in space group and not isomorphous in respect of polymer disposition, is the presence of a short crystallographic axis (about 4 Š) as the unit translational repeat distance.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Vic.
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom115
dc.relation.ispartofpageto136
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume42
dc.rights.retentionY
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.titleLewis-Base Adducts of Group 11 Metal(I) Compounds. XLIII : Synthesis and structural systematics of 1:1 copper(I) halide/nitrogen base adducts as [(N-base)1(CuX)1]∞ 'split-stair' polymers (X = Cl, Br, I; N-base = acridine, quinaldine and 2,6-dimethyl- a
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:26:38Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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