dc.contributor.author | HEALY, PC | |
dc.contributor.author | KILDEA, JD | |
dc.contributor.author | SKELTON, BW | |
dc.contributor.author | WHITE, AH | |
dc.date.accessioned | 2017-05-03T11:09:01Z | |
dc.date.available | 2017-05-03T11:09:01Z | |
dc.date.issued | 1989 | |
dc.identifier.issn | 0004-9425 | |
dc.identifier.doi | 10.1071/CH9890115 | |
dc.identifier.uri | http://hdl.handle.net/10072/25000 | |
dc.description.abstract | The complete array of single strand ('split-stair') polymers for the 1 : 1 system CuX/monodentate nitrogen base, L, all X= Cl, Br, I, has now been synthesized and structurally characterized by using the highly hindered pyridine bases, L= acridine and quinaldine . Similar polymers, [ LCuX ] 8, are also obtained with L = 2,6-dimethylpyridine for X = Cl, Br (but not I which is a dimer , [LCuI2CuL]), and for L = 2,4,6- trimethylpyridine, X = Br, I (but not Cl, which is ionic [CuL2]+[CuCl2]-). A general feature of all polymeric structures, although diverse in space group and not isomorphous in respect of polymer disposition, is the presence of a short crystallographic axis (about 4 Š) as the unit translational repeat distance. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | CSIRO Publishing | |
dc.publisher.place | Collingwood, Vic. | |
dc.relation.ispartofstudentpublication | N | |
dc.relation.ispartofpagefrom | 115 | |
dc.relation.ispartofpageto | 136 | |
dc.relation.ispartofjournal | Australian Journal of Chemistry | |
dc.relation.ispartofvolume | 42 | |
dc.rights.retention | Y | |
dc.subject.fieldofresearch | Chemical sciences | |
dc.subject.fieldofresearchcode | 34 | |
dc.title | Lewis-Base Adducts of Group 11 Metal(I) Compounds. XLIII : Synthesis and structural systematics of 1:1 copper(I) halide/nitrogen base adducts as [(N-base)1(CuX)1]∞ 'split-stair' polymers (X = Cl, Br, I; N-base = acridine, quinaldine and 2,6-dimethyl- a | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.date.issued | 2015-05-21T05:26:38Z | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |