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dc.contributor.authorGOTSIS, S
dc.contributor.authorENGELHARDT, LM
dc.contributor.authorHEALY, PC
dc.contributor.authorKILDEA, JD
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:04Z
dc.date.available2017-05-03T11:09:04Z
dc.date.issued1989
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9890923
dc.identifier.urihttp://hdl.handle.net/10072/25001
dc.description.abstractMixed base pyridine (py)/triphenylphosphine adducts of the silver(I) halides, AgX (X = Cl, Br, I), have been synthesized for 1 : 1 : 1 stoichiometry. The three complexes are isomorphous and isostructural, being monoclinic, P21/c, a 蠱1.2, b 蠱6.8, c 蠱6.5 Š, ߠ蠱22 ꠻ the complexes are centrosymmetric 嬠忭 dihalo -bridged dimers , [(PPh3)( py )AgX2Ag( py )(PPh3)1 (Z = 2 dimers ). Although the stoichiometry of the complex itself is as above, an additional unit of pyridine per silver atom is found as solvent in the lattice, implying the unlikelihood of the existence of an independent 1 : 2 : 1 AgX : py : PPh3 molecular series. In addition, the iodide has been isolated as a different C2/m (?) disordered polymorph.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoen_US
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Vic.
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom923
dc.relation.ispartofpageto931
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume42
dc.rights.retentionY
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchcode03
dc.titleLewis-Base adducts of group 11 Metal(I) Compounds. LIV : Synthesis and structural characterization of binuclear µ,µ'-dichloro-, dibromo- and diiodo-bis[(pyridine)(triphenylphosphine)silver(I)] pyridine solvate complexes
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-22T00:07:09Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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