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dc.contributor.authorBusfield, Kenen_US
dc.contributor.authorEngelhardt, Lutz M.en_US
dc.contributor.authorHealy, Peteren_US
dc.contributor.authorJenkins, Ianen_US
dc.contributor.authorH. White, Allanen_US
dc.date.accessioned2017-05-03T11:09:17Z
dc.date.available2017-05-03T11:09:17Z
dc.date.issued1986en_US
dc.identifier.issn00049425en_US
dc.identifier.doi10.1071/CH9860357en_US
dc.identifier.urihttp://hdl.handle.net/10072/25007
dc.description.abstractThe structures of the title nitroxide , C12H16NO (1), and the alkoxy amine derivative, C18H24N2O2 (2), have been determined by single-crystal X-ray structural analyses. Crystals of (1) are monoclinic, space group Cc with a 11.585(6), b 11.697(10), c 16.753(8)?, ߠ94.33(6)ଠZ 8; R was 0.064 for 1226 independent reflections. The -C(NO)C- group is essentially planar (sum trigonal angles 359.9, 359.9ଠas is the five- membered ring. The N-O distances are 1.249(6), 1.252(8)?. Crystals of (2) are monoclinic, space group P21/c, a 8.295(2), b 13.567(5), c 15.294(3)?, ߠ98.82(2)ଠZ 4; R was 0.051 for 1445 independent reflections. By contrast to (1) the geometry about the nitrogen atom is pyramidal (sum trigonal angles 328੬ and the corresponding five-membered ring has an envelope conformation with a nitrogen displacement of 0.45?. The N-O distance is 1.439(4)?. The high-resolution solid state 13C n.m.r . spectrum of (2) is discussed in relation to the X-ray structure.en_US
dc.description.peerreviewedYesen_US
dc.description.publicationstatusYesen_US
dc.languageEnglishen_US
dc.language.isoen_US
dc.publisherCSIRO Publishingen_US
dc.publisher.placeCollingwood, Australiaen_US
dc.relation.ispartofstudentpublicationNen_US
dc.relation.ispartofpagefrom357en_US
dc.relation.ispartofpageto365en_US
dc.relation.ispartofjournalAustralian Journal of Chemistryen_US
dc.relation.ispartofvolume39en_US
dc.rights.retentionYen_US
dc.subject.fieldofresearchcode250105en_US
dc.titleThe structures of the free-radical scavenger 1,1,3,3-tetramethylisoindolin-2-yloxyl, and of the alkoxy amine derivative 5-(1,1,3,3-tetramethylisoindolin-2-yloxy)-1-vinylpyrrolidin-2-oneen_US
dc.typeJournal articleen_US
dc.type.descriptionC1 - Peer Reviewed (HERDC)en_US
dc.type.codeC - Journal Articlesen_US
gro.facultyGriffith Sciences, School of Natural Sciencesen_US
gro.date.issued2015-05-21T05:27:08Z
gro.hasfulltextNo Full Text


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