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dc.contributor.authorBUSFIELD, WK
dc.contributor.authorENGELHARDT, LM
dc.contributor.authorHEALY, PC
dc.contributor.authorJENKINS, ID
dc.contributor.authorTHANG, SH
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:17Z
dc.date.available2017-05-03T11:09:17Z
dc.date.issued1986
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9860357
dc.identifier.urihttp://hdl.handle.net/10072/25007
dc.description.abstractThe structures of the title nitroxide , C12H16NO (1), and the alkoxy amine derivative, C18H24N2O2 (2), have been determined by single-crystal X-ray structural analyses. Crystals of (1) are monoclinic, space group Cc with a 11.585(6), b 11.697(10), c 16.753(8)?, ߠ94.33(6)ଠZ 8; R was 0.064 for 1226 independent reflections. The -C(NO)C- group is essentially planar (sum trigonal angles 359.9, 359.9ଠas is the five- membered ring. The N-O distances are 1.249(6), 1.252(8)?. Crystals of (2) are monoclinic, space group P21/c, a 8.295(2), b 13.567(5), c 15.294(3)?, ߠ98.82(2)ଠZ 4; R was 0.051 for 1445 independent reflections. By contrast to (1) the geometry about the nitrogen atom is pyramidal (sum trigonal angles 328੬ and the corresponding five-membered ring has an envelope conformation with a nitrogen displacement of 0.45?. The N-O distance is 1.439(4)?. The high-resolution solid state 13C n.m.r . spectrum of (2) is discussed in relation to the X-ray structure.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoen_US
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Australia
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom357
dc.relation.ispartofpageto365
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume39
dc.rights.retentionY
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchcode03
dc.titleThe structures of the free-radical scavenger 1,1,3,3-tetramethylisoindolin-2-yloxyl, and of the alkoxy amine derivative 5-(1,1,3,3-tetramethylisoindolin-2-yloxy)-1-vinylpyrrolidin-2-one
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.facultyGriffith Sciences, School of Natural Sciences
gro.date.issued2015-05-21T05:27:08Z
gro.hasfulltextNo Full Text
gro.griffith.authorJenkins, Ian D.
gro.griffith.authorBusfield, Ken K.
gro.griffith.authorHealy, Peter C.
gro.griffith.authorThang, San


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