dc.contributor.author | ENGELHARDT, LM | |
dc.contributor.author | HEALY, PC | |
dc.contributor.author | SKELTON, BW | |
dc.contributor.author | WHITE, AH | |
dc.date.accessioned | 2017-05-03T11:09:02Z | |
dc.date.available | 2017-05-03T11:09:02Z | |
dc.date.issued | 1989 | |
dc.identifier.issn | 0004-9425 | |
dc.identifier.doi | 10.1071/CH9890885 | |
dc.identifier.uri | http://hdl.handle.net/10072/25019 | |
dc.description.abstract | A variety of heterobimetallic adducts formed between tris(dithiocarbarnato)cobalt(lII) complexes and copper(1) halides have been recorded. In the present paper, reports of the synthesis and structure determinations of [Rh {S2CN(CH2)4}3]3Cul (1), [Cr(S2CNEt2)3]. [Cr(S2CNEt2)3] and [Cr{S2CN(CH2)4}3].3Cul.MeCN (3), similar to cobalt(llI) counterparts, suggest that, in principle, the previously described chemistry of the cobalt(III) systems may be extended to analogous systems for dithiocarbamates of any non-labile trivalent metal. The novel Cu3I3 ring of (3) is disordered between possible boat forms. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | CSIRO Publishing | |
dc.publisher.place | Collingwood, Vic. | |
dc.relation.ispartofstudentpublication | N | |
dc.relation.ispartofpagefrom | 885 | |
dc.relation.ispartofpageto | 893 | |
dc.relation.ispartofjournal | Australian Journal of Chemistry | |
dc.relation.ispartofvolume | 42 | |
dc.rights.retention | Y | |
dc.subject.fieldofresearch | Chemical sciences | |
dc.subject.fieldofresearchcode | 34 | |
dc.title | Lewis-base adducts of group 11 metal(I) compounds. L : Heterobimetallic tris(dithiocarbamato)metal(III)/copper(I) iodide adducts [metal(III) = Cr, Rh] | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.date.issued | 2015-05-21T05:26:46Z | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |