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dc.contributor.authorEngelhardt, Lutz M.en_US
dc.contributor.authorHealy, Peteren_US
dc.contributor.authorW. Skelton, Brianen_US
dc.contributor.authorH. White, Allanen_US
dc.date.accessioned2017-05-03T11:09:02Z
dc.date.available2017-05-03T11:09:02Z
dc.date.issued1989en_US
dc.identifier.issn00049425en_US
dc.identifier.doi10.1071/CH9890885en_US
dc.identifier.urihttp://hdl.handle.net/10072/25019
dc.description.abstractA variety of heterobimetallic adducts formed between tris(dithiocarbarnato)cobalt(lII) complexes and copper(1) halides have been recorded. In the present paper, reports of the synthesis and structure determinations of [Rh {S2CN(CH2)4}3]3Cul (1), [Cr(S2CNEt2)3]. [Cr(S2CNEt2)3] and [Cr{S2CN(CH2)4}3].3Cul.MeCN (3), similar to cobalt(llI) counterparts, suggest that, in principle, the previously described chemistry of the cobalt(III) systems may be extended to analogous systems for dithiocarbamates of any non-labile trivalent metal. The novel Cu3I3 ring of (3) is disordered between possible boat forms.en_US
dc.description.peerreviewedYesen_US
dc.description.publicationstatusYesen_US
dc.languageEnglishen_US
dc.language.isoen_US
dc.publisherCSIRO Publishingen_US
dc.publisher.placeCollingwood, Vic.en_US
dc.relation.ispartofstudentpublicationNen_US
dc.relation.ispartofpagefrom885en_US
dc.relation.ispartofpageto893en_US
dc.relation.ispartofjournalAustralian Journal of Chemistryen_US
dc.relation.ispartofvolume42en_US
dc.rights.retentionYen_US
dc.subject.fieldofresearchcode250105en_US
dc.titleLewis-base adducts of group 11 metal(I) compounds. L : Heterobimetallic tris(dithiocarbamato)metal(III)/copper(I) iodide adducts [metal(III) = Cr, Rh]en_US
dc.typeJournal articleen_US
dc.type.descriptionC1 - Peer Reviewed (HERDC)en_US
dc.type.codeC - Journal Articlesen_US
gro.date.issued2015-05-21T05:26:46Z
gro.hasfulltextNo Full Text


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