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dc.contributor.authorENGELHARDT, LM
dc.contributor.authorHEALY, PC
dc.contributor.authorSKELTON, BW
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:02Z
dc.date.available2017-05-03T11:09:02Z
dc.date.issued1989
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9890885
dc.identifier.urihttp://hdl.handle.net/10072/25019
dc.description.abstractA variety of heterobimetallic adducts formed between tris(dithiocarbarnato)cobalt(lII) complexes and copper(1) halides have been recorded. In the present paper, reports of the synthesis and structure determinations of [Rh {S2CN(CH2)4}3]3Cul (1), [Cr(S2CNEt2)3]. [Cr(S2CNEt2)3] and [Cr{S2CN(CH2)4}3].3Cul.MeCN (3), similar to cobalt(llI) counterparts, suggest that, in principle, the previously described chemistry of the cobalt(III) systems may be extended to analogous systems for dithiocarbamates of any non-labile trivalent metal. The novel Cu3I3 ring of (3) is disordered between possible boat forms.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoen_US
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Vic.
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom885
dc.relation.ispartofpageto893
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume42
dc.rights.retentionY
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchcode03
dc.titleLewis-base adducts of group 11 metal(I) compounds. L : Heterobimetallic tris(dithiocarbamato)metal(III)/copper(I) iodide adducts [metal(III) = Cr, Rh]
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:26:46Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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