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dc.contributor.authorENGELHARDT, LM
dc.contributor.authorHEALY, PC
dc.contributor.authorSKELTON, BW
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:02Z
dc.date.available2017-05-03T11:09:02Z
dc.date.issued1989
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9890885
dc.identifier.urihttp://hdl.handle.net/10072/25019
dc.description.abstractA variety of heterobimetallic adducts formed between tris(dithiocarbarnato)cobalt(lII) complexes and copper(1) halides have been recorded. In the present paper, reports of the synthesis and structure determinations of [Rh {S2CN(CH2)4}3]3Cul (1), [Cr(S2CNEt2)3]. [Cr(S2CNEt2)3] and [Cr{S2CN(CH2)4}3].3Cul.MeCN (3), similar to cobalt(llI) counterparts, suggest that, in principle, the previously described chemistry of the cobalt(III) systems may be extended to analogous systems for dithiocarbamates of any non-labile trivalent metal. The novel Cu3I3 ring of (3) is disordered between possible boat forms.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Vic.
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom885
dc.relation.ispartofpageto893
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume42
dc.rights.retentionY
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.titleLewis-base adducts of group 11 metal(I) compounds. L : Heterobimetallic tris(dithiocarbamato)metal(III)/copper(I) iodide adducts [metal(III) = Cr, Rh]
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:26:46Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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