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dc.contributor.authorENGELHARDT, LM
dc.contributor.authorHEALY, PC
dc.contributor.authorPATRICK, VA
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:15Z
dc.date.available2017-05-03T11:09:15Z
dc.date.issued1987
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9871873
dc.identifier.urihttp://hdl.handle.net/10072/25025
dc.description.abstract3 : 1 adducts of triphenylphosphine, PPh3, with silver halides, AgX, have been characterized for chloride, bromide and iodide by single-crystal X-ray structure determinations, the chloride as its diacetone solvate. Crystals of the chloride, [(PPh3)3AgCl].2(CH3)2CO, are triclinic, P1, a 13.654(4), b 14.059(4), c 13.970(4) Ŭ a 84.82(2), ߠ87.71(2), ? 75.68(2)ꬠZ 2; the structure was refined to a residual R of 0.061 for No = 2428 independent 'observed' reflections. Crystals of the bromide, [(PPh3)3AgBr], are trigonal, P3, a l9.366(6), c 10.787(6) Ŭ Z 3, R was 0.054 for No = 2362. Crystals of the iodide, [(PPh3)3AgI], are monoclinic, P2l/n, a 18.993(8), b 13.807(4), c 17.781(8) Ŭ ߠ96.11(4)ꬠZ 4; R was 0.042 for No = 3691. Ag-Cl, Br, I respectively are 2.533(4), 2.671(6)-2.691(4) and 2.858(1) Ů Ag-P for each of the three structures respectively lie in the ranges 2.558(5)-2.582(4), 2.528(3)-2.549(7)and 2.544(2)-2.780(3) Ů
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Australia
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom1873
dc.relation.ispartofpageto1880
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume40
dc.rights.retentionY
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.titleLewis-base adducts of group 11 metal(I) compounds. XXX : 3:1 complexes of triphenylphosphine with silver(I) halides
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:26:53Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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