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dc.contributor.authorHEALY, PC
dc.contributor.authorPATRICK, JM
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:27Z
dc.date.available2017-05-03T11:09:27Z
dc.date.issued1984
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9841111
dc.identifier.urihttp://hdl.handle.net/10072/25031
dc.description.abstractThe crystal structure of the title compound, [Cu(OH2)2(phen)] (SO4) (phen = 1,10-phenanthroline), has been determined by single-crystal X-ray diffraction methods at room temperature, being refined by full matrix least-squares methods to a residual of 0.033 for 1445 'observed' reflections. Crystals are monoclinic, C2/c, a 14.883(8), b 13.843(9), c 7.019(4) Ŭ ߠ108.60(4)ꬠZ 4. As in a number of other copper(II) and nickel(II) derivatives with (CuL4)(SO4) stoichiometry, the pseudo-square planar copper environments [Cu-N,O: 2.009(2), 1.970(2) Šin the present case] are bridged through the two axial coordination positions by sulfate groups: O.SO2.O[Cu(OH2)2(phen)]O.SO2.0, etc. to give a linear polymeric array [Cu-O(SO4), 2.468(3) ŝ; a crystallographic twofold axis passes through the copper atom.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoen_US
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Australia
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom1111
dc.relation.ispartofpageto1115
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume37
dc.rights.retentionY
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchcode03
dc.titleCrystal structure of diaqua(1,10-phenanthroline)copper(II) sulphate
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:27:59Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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