• myGriffith
    • Staff portal
    • Contact Us⌄
      • Future student enquiries 1800 677 728
      • Current student enquiries 1800 154 055
      • International enquiries +61 7 3735 6425
      • General enquiries 07 3735 7111
      • Online enquiries
      • Staff phonebook
    View Item 
    •   Home
    • Griffith Research Online
    • Journal articles
    • View Item
    • Home
    • Griffith Research Online
    • Journal articles
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

  • All of Griffith Research Online
    • Communities & Collections
    • Authors
    • By Issue Date
    • Titles
  • This Collection
    • Authors
    • By Issue Date
    • Titles
  • Statistics

  • Most Popular Items
  • Statistics by Country
  • Most Popular Authors
  • Support

  • Contact us
  • FAQs
  • Admin login

  • Login
  • Lewis-Base Adducts of Group 11 Metal(I) Compounds. XXXIV : 1:2 silver(I) halide/monodentate amine complexes. A novel structural type in 1:2 silver(I) chloride/piperidine

    Author(s)
    HEALY, PC
    KILDEA, JD
    WHITE, AH
    Griffith University Author(s)
    Healy, Peter C.
    Year published
    1988
    Metadata
    Show full item record
    Abstract
    Recrystallization of silver(I) chloride from neat piperidine (L) yields a 1 : 2 adduct, characterized by a single-crystal X-ray study. Crystals are monoclinic, C2/c, a 20.76(4), b 6.422(7), c 20.69(2)?, ߠ96.9(1)ଠZ 8; R 0.042 for 1061 'observed' reflections. The structure, the first determined for a 1 : 2 silver(I) chloride/monodentate amine adduct, is an infinite one-dimensional chloro-bridged polymer -AgL2-Cl-AgL2-Cl-. About the four-coordinate silver atom, Ag-Cl are 2.524(3), 2.667(3)?, Ag-N 2.385(9), 2.347(11)?, with Ag-Cl-Ag 102.62(9)໠the largest angle in the silver environment is 120.3(2)ਃl-Ag-N).Recrystallization of silver(I) chloride from neat piperidine (L) yields a 1 : 2 adduct, characterized by a single-crystal X-ray study. Crystals are monoclinic, C2/c, a 20.76(4), b 6.422(7), c 20.69(2)?, ߠ96.9(1)ଠZ 8; R 0.042 for 1061 'observed' reflections. The structure, the first determined for a 1 : 2 silver(I) chloride/monodentate amine adduct, is an infinite one-dimensional chloro-bridged polymer -AgL2-Cl-AgL2-Cl-. About the four-coordinate silver atom, Ag-Cl are 2.524(3), 2.667(3)?, Ag-N 2.385(9), 2.347(11)?, with Ag-Cl-Ag 102.62(9)໠the largest angle in the silver environment is 120.3(2)ਃl-Ag-N).
    View less >
    Journal Title
    Australian Journal of Chemistry
    Volume
    41
    DOI
    https://doi.org/10.1071/CH9880417
    Subject
    Chemical sciences
    Publication URI
    http://hdl.handle.net/10072/25039
    Collection
    • Journal articles

    Footer

    Disclaimer

    • Privacy policy
    • Copyright matters
    • CRICOS Provider - 00233E
    • TEQSA: PRV12076

    Tagline

    • Gold Coast
    • Logan
    • Brisbane - Queensland, Australia
    First Peoples of Australia
    • Aboriginal
    • Torres Strait Islander