dc.contributor.author | ENGELHARDT, LM | |
dc.contributor.author | HEALY, PC | |
dc.contributor.author | SKELTON, BW | |
dc.contributor.author | WHITE, AH | |
dc.date.accessioned | 2017-05-03T11:09:10Z | |
dc.date.available | 2017-05-03T11:09:10Z | |
dc.date.issued | 1988 | |
dc.identifier.issn | 0004-9425 | |
dc.identifier.doi | 10.1071/CH9880839 | |
dc.identifier.uri | http://hdl.handle.net/10072/25040 | |
dc.description.abstract | Reaction of copper(I) iodide with tris (N,N- dipropyl -and N, N- diisopropyl-dithiocarbamato )cobalt(III), [Co(S2CNR2)3 = Co( dtc )3](R = Pr or Pri ), yields 1:1 adducts which have been characterized by single-crystal X-ray structure determination. Crystals of the propyl species are monoclinic, P21/c, a 13.722(7), b 16.854(7), c 16.787(8)?, ߠ121.66(3)ଠR was 0.056 for No 2834 'observed' reflections. The isopropyl derivative is orthorhombic, Ccca , a 33.93 (1), b 13.616(8), c 14.574(5)?; R was 0.075 for No 726. Each adduct is dimeric [Co( dtc )3](CuI2Cu)[Co( dtc )3]; the propyl derivative has crystallographically imposed i symmetry, whereas the isopropyl adduct has quasi-222 symmetry. Thus, the chiralities of the pair of Co( dtc )3 moieties in the dipropyl adduct are opposite, whereas in the isopropyl adduct they are the same. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | CSIRO Publishing | |
dc.publisher.place | Collingwood, Vic. | |
dc.relation.ispartofstudentpublication | N | |
dc.relation.ispartofpagefrom | 839 | |
dc.relation.ispartofpageto | 844 | |
dc.relation.ispartofjournal | Australian Journal of Chemistry | |
dc.relation.ispartofvolume | 41 | |
dc.rights.retention | Y | |
dc.subject.fieldofresearch | Chemical sciences | |
dc.subject.fieldofresearchcode | 34 | |
dc.title | Lewis-Base Adducts of Group 11 Metal(I) Compounds. XXXVII : A novel isomerism in the heterobimetallic 1:1 adducts of copper(I) halides with tris(dithiocarbamato)cobalt(III) | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.date.issued | 2015-05-21T05:35:00Z | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |