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dc.contributor.authorENGELHARDT, LM
dc.contributor.authorHEALY, PC
dc.contributor.authorSKELTON, BW
dc.contributor.authorWHITE, AH
dc.date.accessioned2017-05-03T11:09:10Z
dc.date.available2017-05-03T11:09:10Z
dc.date.issued1988
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH9880839
dc.identifier.urihttp://hdl.handle.net/10072/25040
dc.description.abstractReaction of copper(I) iodide with tris (N,N- dipropyl -and N, N- diisopropyl-dithiocarbamato )cobalt(III), [Co(S2CNR2)3 = Co( dtc )3](R = Pr or Pri ), yields 1:1 adducts which have been characterized by single-crystal X-ray structure determination. Crystals of the propyl species are monoclinic, P21/c, a 13.722(7), b 16.854(7), c 16.787(8)?, ߠ121.66(3)ଠR was 0.056 for No 2834 'observed' reflections. The isopropyl derivative is orthorhombic, Ccca , a 33.93 (1), b 13.616(8), c 14.574(5)?; R was 0.075 for No 726. Each adduct is dimeric [Co( dtc )3](CuI2Cu)[Co( dtc )3]; the propyl derivative has crystallographically imposed i symmetry, whereas the isopropyl adduct has quasi-222 symmetry. Thus, the chiralities of the pair of Co( dtc )3 moieties in the dipropyl adduct are opposite, whereas in the isopropyl adduct they are the same.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoen_US
dc.publisherCSIRO Publishing
dc.publisher.placeCollingwood, Vic.
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom839
dc.relation.ispartofpageto844
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume41
dc.rights.retentionY
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchcode03
dc.titleLewis-Base Adducts of Group 11 Metal(I) Compounds. XXXVII : A novel isomerism in the heterobimetallic 1:1 adducts of copper(I) halides with tris(dithiocarbamato)cobalt(III)
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:35:00Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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