dc.contributor.author | HEALY, PC | |
dc.contributor.author | PAKAWATCHAI, C | |
dc.contributor.author | WHITE, AH | |
dc.date.accessioned | 2017-05-03T11:09:19Z | |
dc.date.available | 2017-05-03T11:09:19Z | |
dc.date.issued | 1985 | |
dc.identifier.issn | 0004-9425 | |
dc.identifier.doi | 10.1071/CH9850669 | |
dc.identifier.uri | http://hdl.handle.net/10072/25042 | |
dc.description.abstract | The crystal structure of [C13H10N] [CuCl3(C13H9N)].H2O(C13H9N = acridine ) has been determined by single-crystal X-ray diffraction methods at 295 K, being refined by least squares to a residual of 0.037 for 1942 independent 'observed' reflections. Crystals are triclinic, Pi , a 16.27(2), b 10.080(8), c 7.236(5) ?, a 88.85(6), ߠ82.68(8), ? 81.12(9)ଠZ 2. The metal atom stereochemistry is unusual, being of pseudo-m symmetry; one of the chlorine atoms is coplanar with the copper and the acridine [Cu- Cl 2.237(2) ?, N-Cu- Cl 143.5(1)ݬ with the other two disposed to either side of that plane [Cu- Cl 2.252(3), 2.243(2) ?; Cl-Cu-Cl 145.62(7)ݮ Cu-N is 2.018(5) ?. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | CSIRO Publishing | |
dc.publisher.place | Collingwood, Australia | |
dc.relation.ispartofstudentpublication | N | |
dc.relation.ispartofpagefrom | 669 | |
dc.relation.ispartofpageto | 675 | |
dc.relation.ispartofjournal | Australian Journal of Chemistry | |
dc.relation.ispartofvolume | 38 | |
dc.rights.retention | Y | |
dc.subject.fieldofresearch | Chemical sciences | |
dc.subject.fieldofresearchcode | 34 | |
dc.title | Structural characterization of a [Cl3CuL]- (L = nitrogen base) species. A novel coordination environment for copper(II) | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.date.issued | 2015-05-21T05:35:10Z | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |