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dc.contributor.authorGREGSON, AK
dc.contributor.authorDODDRELL, DM
dc.contributor.authorHEALY, PC
dc.date.accessioned2017-05-03T11:09:34Z
dc.date.available2017-05-03T11:09:34Z
dc.date.issued1978
dc.date.modified2009-08-06T06:08:20Z
dc.identifier.issn0020-1669
dc.identifier.doi10.1021/ic50183a025
dc.identifier.urihttp://hdl.handle.net/10072/25046
dc.description.abstractThe low-temperature (2-100 K) polycrystalline magnetic properties of V ( a ~ a c )M~ ,n ( a ~ a c )a~n,d Mn(trop)3 are reported [Hacac = 2,4-pentanedione and Htrop = tropolone]. For V(acac), the zero-field splitting (D) is 7.7 cm-', gI1 = 1.96 and g , = 1.78, all compatible with the reinterpreted optical spectrum. The magnetic data for Mn ( a ~ a c h) a~v e been interpreted with D = 3.1 cm-' and g = 2.00 and are also compatible with ligand field calculations based on the reinterpreted optical spectrum. In Mn(trop), there appears to be a very weak intermolecular coupling through the tropolonate ligands, the magnetic parameters being D = -2.6 cm-], g = 2.00, and J = -0.18 cm-l.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.publisher.placeUnited States
dc.publisher.urihttp://pubs.acs.org/journal/inocaj
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom1216
dc.relation.ispartofpageto1219
dc.relation.ispartofissue5
dc.relation.ispartofjournalInorganic Chemistry
dc.relation.ispartofvolume17
dc.rights.retentionY
dc.subject.fieldofresearchInorganic chemistry
dc.subject.fieldofresearchPhysical chemistry
dc.subject.fieldofresearchOther chemical sciences
dc.subject.fieldofresearchcode3402
dc.subject.fieldofresearchcode3406
dc.subject.fieldofresearchcode3499
dc.titleLow-temperature magnetic properties of three vanadium(III) and manganese(III) β-diketonate complexes
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.rights.copyright© 1978 American Chemical Society. Self-archiving of the author-manuscript version is not yet supported by this publisher. The contents of this journal can be freely accessed online via the ACS web page 12 months after publication. Use hypertext link above to access the ACS website.
gro.date.issued1978
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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