4-(Benzylideneamino)benzenesulfonamide
Abstract
The crystal structure of the title compound, [Ru(C10H15)(C7H9NO2S)]C24H20B, has been determined as part of our investigation into the structural and biological properties of organometallic RuII-arene-Cp* complex salts of the type [R-PhRuCp*]+瘭 (where Cp* is pentamethylcyclopentadiene). Tethering the RuCp* group to the benzene ring of p-toluenesulfonamide results in only minor changes to the molecular geometry of the sulfonamide, but, together with crystallization as the [BPh4]- salt, effectively blocks involvement of the sulfonamide group in N-H...O hydrogen-bonding networks.
Journal Title
Acta Crystallographica. Section E: Structure reports online
Volume
E65
Publisher URI
Copyright Statement
© The Author(s) 2008. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
Subject
Chemical sciences