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  • Regioselective green anomeric deacetylation catalyzed by lanthanide triflates

    Author(s)
    Tran, Anh Tuan
    Deydier, Sophie
    Bonnaffe, David
    Narvor, Christine
    Griffith University Author(s)
    Deydier, Sophie
    Year published
    2008
    Metadata
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    Abstract
    Lanthanide triflates, especially Nd(OTf)3, efficiently catalyze the regioselective transesterification of anomeric acetates. This method offers an efficient solution for the otherwise difficult removal of methyl uronates anomeric acetates as well as a green alternative to published protocols since the lanthanide catalysts are non-toxic and may be easily recycled and reused.Lanthanide triflates, especially Nd(OTf)3, efficiently catalyze the regioselective transesterification of anomeric acetates. This method offers an efficient solution for the otherwise difficult removal of methyl uronates anomeric acetates as well as a green alternative to published protocols since the lanthanide catalysts are non-toxic and may be easily recycled and reused.
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    Journal Title
    Tetrahedron Letters
    Volume
    49
    Issue
    13
    DOI
    https://doi.org/10.1016/j.tetlet.2008.01.106
    Subject
    Organic Green Chemistry
    Medicinal and Biomolecular Chemistry
    Organic Chemistry
    Publication URI
    http://hdl.handle.net/10072/26534
    Collection
    • Journal articles

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