dc.contributor.author | Ainscough, EW | |
dc.contributor.author | Brodie, AM | |
dc.contributor.author | Healy, PC | |
dc.contributor.author | Waters, JM | |
dc.date.accessioned | 2017-05-03T13:46:03Z | |
dc.date.available | 2017-05-03T13:46:03Z | |
dc.date.issued | 2000 | |
dc.identifier.issn | 0004-9425 | |
dc.identifier.doi | 10.1071/CH00145 | |
dc.identifier.uri | http://hdl.handle.net/10072/3173 | |
dc.description.abstract | The X-ray crystal structure determination of bis[-(phenylcyanamido)bis(triphenylphosphine)copper(I)], [{Cu(PPh3)2(C6H5NCN)}2], (1) is reported. The complex has a centrosymmetric dimeric structure with the phenylcyanamide ligands bridging the copper atoms in a -1,3-fashion. The structure is compared with that of the 4-methylphenylcyanamido complex, [{Cu(PPh3)2(4-MeC6H4NCN)}2] (2), and the differences observed in the Cu-P bond lengths compared with changes in the solid state 31P cross-polarization magic-angle spinning (CPMAS) spectra of the two complexes. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | CSIRO Publishing | |
dc.publisher.place | Australia | |
dc.relation.ispartofpagefrom | 971 | |
dc.relation.ispartofpageto | 973 | |
dc.relation.ispartofjournal | Australian Journal of Chemistry | |
dc.relation.ispartofvolume | 53 | |
dc.subject.fieldofresearch | Chemical sciences | |
dc.subject.fieldofresearch | History, heritage and archaeology | |
dc.subject.fieldofresearchcode | 34 | |
dc.subject.fieldofresearchcode | 43 | |
dc.title | Structural Properties of a Dimeric Phenylcyanamidocopper(1) Complex, [{Cu(PPh3)2(C6H5NCN)}2] | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.date.issued | 2015-05-21T02:43:18Z | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |