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dc.contributor.authorAinscough, EW
dc.contributor.authorBrodie, AM
dc.contributor.authorHealy, PC
dc.contributor.authorWaters, JM
dc.date.accessioned2017-05-03T13:46:03Z
dc.date.available2017-05-03T13:46:03Z
dc.date.issued2000
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH00145
dc.identifier.urihttp://hdl.handle.net/10072/3173
dc.description.abstractThe X-ray crystal structure determination of bis[-(phenylcyanamido)bis(triphenylphosphine)copper(I)], [{Cu(PPh3)2(C6H5NCN)}2], (1) is reported. The complex has a centrosymmetric dimeric structure with the phenylcyanamide ligands bridging the copper atoms in a -1,3-fashion. The structure is compared with that of the 4-methylphenylcyanamido complex, [{Cu(PPh3)2(4-MeC6H4NCN)}2] (2), and the differences observed in the Cu-P bond lengths compared with changes in the solid state 31P cross-polarization magic-angle spinning (CPMAS) spectra of the two complexes.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherCSIRO Publishing
dc.publisher.placeAustralia
dc.relation.ispartofpagefrom971
dc.relation.ispartofpageto973
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume53
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchHistory, heritage and archaeology
dc.subject.fieldofresearchcode34
dc.subject.fieldofresearchcode43
dc.titleStructural Properties of a Dimeric Phenylcyanamidocopper(1) Complex, [{Cu(PPh3)2(C6H5NCN)}2]
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T02:43:18Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.


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