dc.contributor.author | Aldabbagh, F | |
dc.contributor.author | Busfield, WK | |
dc.contributor.author | Jenkins, ID | |
dc.contributor.author | Thang, SH | |
dc.date.accessioned | 2017-05-03T13:46:06Z | |
dc.date.available | 2017-05-03T13:46:06Z | |
dc.date.issued | 2000 | |
dc.identifier.issn | 0040-4039 | |
dc.identifier.doi | 10.1016/S0040-4039(00)00440-8 | |
dc.identifier.uri | http://hdl.handle.net/10072/3181 | |
dc.description.abstract | At elevated temperatures, nitroxides (e.g. 1,1,3,3-tetramethyl-2,3-dihydroisoindol-2-yloxyl) undergo a slow addition reaction with acrylonitrile, methyl acrylate and styrene to give the bis-nitroxide adducts. With alkenes containing an allylic hydrogen such as methyl methacrylate and 6-methylene-1,4-oxathiepan-7-one, the major reaction observed was hydrogen abstraction. The resulting hydroxylamines can be trapped as Michael addition products. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | Pergamon | |
dc.publisher.place | UK | |
dc.relation.ispartofpagefrom | 3673 | |
dc.relation.ispartofpageto | 3676 | |
dc.relation.ispartofjournal | Tetrahedron Letters | |
dc.relation.ispartofvolume | 41 | |
dc.subject.fieldofresearch | Medicinal and biomolecular chemistry | |
dc.subject.fieldofresearch | Organic chemistry | |
dc.subject.fieldofresearch | History, heritage and archaeology | |
dc.subject.fieldofresearchcode | 3404 | |
dc.subject.fieldofresearchcode | 3405 | |
dc.subject.fieldofresearchcode | 43 | |
dc.title | The reactivity of nitroxides towards alkenes | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.faculty | An Unassigned Group, An Unassigned Department | |
gro.date.issued | 2015-05-11T00:48:49Z | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Jenkins, Ian D. | |