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dc.contributor.authorAldabbagh, F
dc.contributor.authorBusfield, WK
dc.contributor.authorJenkins, ID
dc.contributor.authorThang, SH
dc.date.accessioned2017-05-03T13:46:06Z
dc.date.available2017-05-03T13:46:06Z
dc.date.issued2000
dc.identifier.issn0040-4039
dc.identifier.doi10.1016/S0040-4039(00)00440-8
dc.identifier.urihttp://hdl.handle.net/10072/3181
dc.description.abstractAt elevated temperatures, nitroxides (e.g. 1,1,3,3-tetramethyl-2,3-dihydroisoindol-2-yloxyl) undergo a slow addition reaction with acrylonitrile, methyl acrylate and styrene to give the bis-nitroxide adducts. With alkenes containing an allylic hydrogen such as methyl methacrylate and 6-methylene-1,4-oxathiepan-7-one, the major reaction observed was hydrogen abstraction. The resulting hydroxylamines can be trapped as Michael addition products.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherPergamon
dc.publisher.placeUK
dc.relation.ispartofpagefrom3673
dc.relation.ispartofpageto3676
dc.relation.ispartofjournalTetrahedron Letters
dc.relation.ispartofvolume41
dc.subject.fieldofresearchMedicinal and biomolecular chemistry
dc.subject.fieldofresearchOrganic chemistry
dc.subject.fieldofresearchHistory, heritage and archaeology
dc.subject.fieldofresearchcode3404
dc.subject.fieldofresearchcode3405
dc.subject.fieldofresearchcode43
dc.titleThe reactivity of nitroxides towards alkenes
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.facultyAn Unassigned Group, An Unassigned Department
gro.date.issued2015-05-11T00:48:49Z
gro.hasfulltextNo Full Text
gro.griffith.authorJenkins, Ian D.


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